THE NORPHTHALOCYANINES BEARING TWO TTF UNITS: SYNTHESIS, PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES

被引：5
作者：
Hou, Ruibin [1 ]
Jiang, Cuiping [1 ]
Chen, Tie [1 ]
Jin, Long-Yi [1 ]
Yin, Bingzhu [1 ]
机构：
[1] Yanbian Univ, Key Lab Nat Resources Changbai Mt & Funct Mol, Minist Educ, Yanji 133002, Peoples R China
来源：
HETEROCYCLES | 2011年 / 83卷 / 08期
基金：
中国国家自然科学基金;
关键词：
Magnesium Norphthalocyanine; Metal-Free Norphthalocyanine; Tetrathiafulvalene; Phthalonitrile; Dithiomaleionitrile; SOLITAIRE-PORPHYRAZINES; TETRATHIAFULVALENE; PHTHALOCYANINES; COMPLEXES; METALLOPHTHALOCYANINES; TRIAZOLEPHTHALOCYANINES; SUBSTITUENTS; AGGREGATION; MACROCYCLES; CHEMISTRY;
D O I：
10.3987/COM-11-12235
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A magnesium norphthalocyanine (6a) was prepared by the mixed condensation of phthalonitrile in excess with the dithiomaleonitrile bearing two TTF units (5), using Mg(11) as a template. Subsequent demetalation of 6a with acetic acid gave 6b in good yield. The structures of target compounds were determined by EA, NMR and TOF MS and their electrochemical and optical properties were also studied by cyclic voltammetry and UV-vis spectroscopy.
引用
收藏
页码：1859 / 1866
页数：8
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