Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells

被引：322

作者：

Brennaman, M. Kyle ^{[1
]}

Dillon, Robert J. ^{[1
]}

Alibabaei, Leila ^{[1
]}

Gish, Melissa K. ^{[1
]}

Dares, Christopher J. ^{[1
]}

Ashford, Dennis L. ^{[1
]}

House, Ralph L. ^{[1
]}

Meyer, Gerald J. ^{[1
]}

Papanikolas, John M. ^{[1
]}

Meyer, Thomas J. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, CB 3290, Chapel Hill, NC 27599 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 40期

关键词：

INTERFACIAL ELECTRON-TRANSFER; ELECTROCATALYTIC WATER OXIDATION; NANOCRYSTALLINE TIO2 FILMS; ATOMIC LAYER DEPOSITION; FEMTOSECOND TRANSIENT ABSORPTION; PHOTOINDUCED ULTRAFAST DYNAMICS; CHROMOPHORE-CATALYST ASSEMBLIES; ELECTROCHEMICAL CO2 REDUCTION; CONDUCTION-BAND ELECTRONS; CARBON-DIOXIDE REDUCTION;

D O I：

10.1021/jacs.6b06466

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dye-sensitized photoelectrosynthesis cell (DSPEC) integrates high bandgap, nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of designed chromophore-catalyst assemblies. The goals are photoelectrochemical water splitting into hydrogen and oxygen and reduction of CO2 by water to give oxygen and carbon-based fuels. Solar driven water oxidation occurs at a photoanode and water or CO2 reduction at a cathode or photocathode initiated by molecular-level light absorption. Light absorption is followed by electron or hole injection, catalyst activation, and catalytic water oxidation or water/CO2 reduction. The DSPEC is of recent origin but significant progress has been made. It has the potential to play an important role in our energy future.

引用

页码：13085 / 13102

页数：18

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