Multielectron wave-packet propagation: General theory and application

被引：167

作者：

Kuleff, AI ^{[1
]}

Breidbach, J ^{[1
]}

Cederbaum, LS ^{[1
]}

机构：

[1] Heidelberg Univ, PCI, D-69120 Heidelberg, Germany

来源：

JOURNAL OF CHEMICAL PHYSICS | 2005年 / 123卷 / 04期

关键词：

D O I：

10.1063/1.1961341

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An ab initio method for multielectron wave-packet propagation in relatively large systems is presented. It allows the description of ultrafast electron dynamics processes before the coupling with the nuclear motion becomes important. The method is applied to the amino acid glycine for the investigation of the migration of hole charge following the ionization of the system. Two different mechanisms of ultrafast charge migration are identified and discussed. It is shown that the electron correlation can be the driving force for the charge-transfer dynamics in glycine. (C) 2005 American Institute of Physics.

引用

页数：10

共 42 条

[1] THE PRINCIPLE OF MINIMIZED ITERATIONS IN THE SOLUTION OF THE MATRIX EIGENVALUE PROBLEM [J].