Measurements of the Thermal Conductivity of 1,1,1,3,3-Pentafluoropropane (R245fa) and Correlations for the Viscosity and Thermal Conductivity Surfaces

被引:30
作者
Perkins, Richard A. [1 ]
Huber, Marcia L. [1 ]
Assael, Marc J. [2 ]
机构
[1] NIST, Appl Chem & Mat Div, Boulder, CO 80305 USA
[2] Aristotle Univ Thessaloniki, Dept Chem Engn, Lab Thermophys Properties & Environm Proc, Thessaloniki 54636, Greece
关键词
ORGANIC RANKINE-CYCLE; TRANSPORT-PROPERTIES; CRITICAL REGION; FLUIDS; COEFFICIENTS; HFC-245FA; MODEL; HEAT; ORC; RECOVERY;
D O I
10.1021/acs.jced.6b00350
中图分类号
O414.1 [热力学];
学科分类号
摘要
New experimental data on the thermal conductivity of 1,1,1,3,3-pentafluoropropane (R245fa) are reported that cover a wide range of liquid conditions. These new experimental data were made with a transient hot-wire apparatus and cover the liquid phase over a temperature range of 173-344 K and a pressure range of 0.1-71 MPa. The experimental data reported here have an expanded uncertainty (0.95 level of confidence) of less than 1%. The measurements are used with selected literature data to develop correlations for the thermal conductivity. On the basis of this expanded uncertainty and comparisons with experimental data, the thermal conductivity correlation for R245fa is estimated to have a relative expanded uncertainty (0.95 level of confidence) of about 2% at a 95% confidence level for the liquid phase at pressures to 70 MPa and 2% for the vapor phase. In addition, we surveyed literature data and developed a correlation for the viscosity of R245fa. The estimated relative expanded uncertainty (0.95 level of confidence) of this correlation is 3% for the liquid phase at pressures to 40 MPa and 2% for the vapor phase.
引用
收藏
页码:3286 / 3294
页数:9
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