Self-assembly of two discrete polynuclear iron(II) metallomacrocycles from a ligand containing two 2,2′:6′, 2"-terpyridine binding domains

被引：50

作者：

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Smith, CB ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

关键词：

2,2 ': 6 ',2 ''-terpyridine; metallomacrocycle; iron(II);

D O I：

10.1016/S1387-7003(03)00168-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homoditopic ligand L contains two tpy metal-binding domains and reacts with iron(II) chloride to form two multinuclear metallomacrocycles having [3 + 3] and [4 + 4] metal-ligand stoichiometries. (C) 2003 Elsevier Science B.V. All rights reserved.

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页码：1011 / 1013

页数：3

相关论文

共 13 条

[1]

CARGILLTHOMPSON AM, 1997, COORDIN CHEM REV, V160, P1

[2] SYNTHESIS AND COORDINATION BEHAVIOR OF 6',6''-BIS(2-PYRIDYL)-2,2'-4,4''-2'',2'''-QUATERPYRIDINE - BACK-TO-BACK 2,2'-6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

WARD, MD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (04) :1405-1409

[3] Pentaerythritol-based metallodendrimers [J].

Constable, EC ;

Housecroft, CE ;

Cattalini, M ;

Phillips, D .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (02) :193-200

[4] Metal-directed assembly of a box-like structure [J].

Constable, EC ;

Schofield, E .

CHEMICAL COMMUNICATIONS, 1998, (03) :403-404

[5]

Newkome GR, 2002, CHEM-EUR J, V8, P2946, DOI 10.1002/1521-3765(20020703)8:13<2946::AID-CHEM2946>3.0.CO

[6]

2-M

[7] Synthesis of two covalently linked bis(2,2′:6′,2"-terpyridine) (terpy) chelating ligands with different length spacers, comparison of the crystal structures of their mononuclear nickel(II) complexes, and kinetic and mechanistic studies of the reaction of one ligand with [Fe(terpy)2]2+ [J].

Priimov, GU ;

Moore, P ;

Maritim, PK ;

Butalanyi, PK ;

Alcock, NW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (04) :445-449

[8] Monitoring the iron(II)-induced self-assembly of preorganized tritopic ligands by electrospray mass spectrometry: Unique formation of metallomacrocycles [J].

Romero, FM ;

Ziessel, R ;

DupontGervais, A ;

VanDorsselaer, A .

CHEMICAL COMMUNICATIONS, 1996, (04) :551-553

[9]

SAUVAGE JP, 1996, COMPREHENSIVE COORDI, V9

[10] 4′-functionalized 2,2′:6′,2"-terpyridines as building blocks for supramolecular chemistry and nanoscience [J].

Schubert, US ;

Eschbaumer, C ;

Hien, O ;

Andres, PR .

TETRAHEDRON LETTERS, 2001, 42 (28) :4705-4707