Synthesis, structure and redox properties of new cobalt(II) and nickel(II) complexes with 6-ferrocenyl-2,2′-bipyridyl

被引：7

作者：

Goldberg, Anna ^{[1
]}

Kiskin, Mikhail ^{[1
]}

Grinberg, Vitali ^{[2
]}

Kozyukhin, Sergey ^{[1
]}

Bogomyakov, Artem ^{[3
]}

Utepova, Irina ^{[4
]}

Sidorov, Aleksey ^{[1
]}

Chupakhin, Oleg ^{[4
,5
]}

Eremenko, Igor ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia

[3] Russian Acad Sci, Inst Int Tomog Ctr, Siberian Branch, Novosibirsk 630090, Russia

[4] Ural Fed Univ, Ekaterinburg 620002, Russia

[5] Russian Acad Sci, I Ya Postovsky Inst Organ Synth, Ural Branch, Ekaterinburg 620041, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 13期

基金：

俄罗斯基础研究基金会;

关键词：

Heterometallic complexes; Ferrocenyl ligand; X-ray analysis; Electrochemistry; Electronic spectra; ASYMMETRIC CATALYSIS; FERROCENYL; SENSITIZATION; METAL; TIO2;

D O I：

10.1016/j.jorganchem.2011.04.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New ionic complexes [ML2(MeCN)(2)]center dot 2Otf (M = Co or Ni; L = 6-ferrocenyl-2,2'-bipyridyl) were synthesized and characterized by single-crystal X-ray diffraction. Cyclic voltammograms of the compounds [ML2(MeCN)(2)]center dot 2Otf in CH2Cl2 show good cycle stability over 100 cycles in the quasi-reversible oxidation potential range (from -0.25 to 0.5 V). (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：2607 / 2610

页数：4

共 36 条

[1]

[Anonymous], 1994, Sovremennaya magnetokhimiya (Modern Magnetochemistry)

[2]

[Anonymous], 1997, SMART CONTR SAINT IN

[3]

ARICI E, 2003, ADV FUNCT MATER, V2, P13

[4]

Atkinson R.C.J., 2004, CHEM SOC REV, V33, P313

[5] Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand.: Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](AgI)22+/(CuII)24+/(ZnII)24+ [J].

Braga, D ;

Polito, M ;

Bracaccini, M ;

D'Addario, D ;

Tagliavini, E ;

Proserpio, DM ;

Grepioni, F .

CHEMICAL COMMUNICATIONS, 2002, (10) :1080-1081

[6] Electrochemical reduction of cobalt and nickel complexes with ligands stabilizing metal in low oxidation state [J].

Budnikova, YG ;

Kafiyatullina, AG ;

Kargin, YM ;

Sinyashin, OG .

RUSSIAN CHEMICAL BULLETIN, 2003, 52 (07) :1504-1511

[7] Synthesis, structure, and reactivity of new chiral ferrocenyl pyrazole ligands [J].

Burckhardt, U ;

Drommi, D ;

Togni, A .

INORGANICA CHIMICA ACTA, 1999, 296 (01) :183-194

[8] THE SYNTHESIS OF DIPRIDYLFERROCENES AND 1,10-PHENANTHROLYLFERROCENES AND BIS-N,N'-(2,2'-DIPYRIDYL(6-FERROCENYL-N,N'-2,2'-DIPYRIDYL))RUTHENIUM DICHLORIDE [J].

BUTLER, IR ;

ROUSTAN, JL .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (12) :2212-2215

[9] BIPYRIDYL-METAL COMPLEXES .2. SYNTHESIS AND CHARACTERIZATION OF PALLADIUM(II) CHLORIDE COMPLEXES OF 6-FERROCENYL-2,2'-BIPYRIDINE, 2-FERROCENYL-1, 10-PHENANTHROLINE, AND 6-RUTHENOCENYL-2,2'-BIPYRIDINE AND THE SINGLE-CRYSTAL X-RAY STRUCTURE OF (1,1'-BIS(2,2'-BIPYRID-6-YL)FERROCENE-N,N')PALLADIUM CHLORIDE [J].

BUTLER, IR .

ORGANOMETALLICS, 1992, 11 (01) :74-83

[10]

Calabrese J.C., 1991, J AM CHEM SOC, V113, P1221

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