Fluorinated/non-fluorinated bisphenoxy benzyl ether zinc(II) phthalocyanine: Synthesis, photoinduced intramolecular electron transfer and intermolecular energy transfer

被引：5

作者：

Guo, Ruotao ^{[1
]}

Chen, Kuizhi ^{[1
]}

Yu, Zhiqiang ^{[1
]}

Ye, Qiuhao ^{[1
]}

Xiao, Wenling ^{[1
]}

Huang, Bingcheng ^{[1
]}

Guan, Xinqiao ^{[1
]}

Peng, Yiru ^{[1
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Mat, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fujian Prov Key Lab Polymer Mat, Fuzhou 350007, Peoples R China

来源：

JOURNAL OF LUMINESCENCE | 2020年 / 222卷

基金：

中国国家自然科学基金;

关键词：

Fluorinated; Phthalocyanine; Photophysical properties; Photoinduced intramolecular electronic transfer; Photoinduced intramolecular energy transfer; PHOTOCHEMICAL PROPERTIES; PHOTOPROPERTIES; SILICON(IV); DENDRIMERS; FULLERENE; DNA;

D O I：

10.1016/j.jlumin.2020.117163

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Two novel series of fluorinated and non-fluorinated bisphenoxy benzyl ether with cyano/pentyl terminal groups zinc(II) phthalocyanines were synthesized. Their structures were characterized by elemental analysis, IR, H-1 NMR, C-13 NMR, ESI-MS and MALDI-TOF-MS methods. The photophysical properties, photoinduced intramolecular electron transfer, and photoinduced intramolecular energy transfer of fluorinated and non-fluorinated phthalocyanines were compared by UV-Vis and fluorescence spectroscopic methods. These properties exhibited fluorinated substituents and terminal groups nature dependence. Fluorinated zinc(II) phthalocyanine with pentyl ester terminal groups had the highest molar absorption coefficient, fluorescence intensity and fluorescence lifetime. Non-fluorinated zinc(II) phthalocyanine with cyano terminal groups exhibited the highest energy transfer efficiency.

引用

页数：10

共 35 条

[1] Virtual photons, dipole fields and energy transfer: a quantum electrodynamical approach [J].

Andrews, DL ;

Bradshaw, DS .

EUROPEAN JOURNAL OF PHYSICS, 2004, 25 (06) :845-858

[2]

[Anonymous], [No title captured]

[3] Chiral multichromophoric supramolecular nanostructures assembled by single stranded DNA and RNA templates [J].

Balaz, Milan ;

Tannir, Shambhavi ;

Varga, Krisztina .

COORDINATION CHEMISTRY REVIEWS, 2017, 349 :66-83

[4] Fluorinated coumarin silicon(IV) / zinc(II) phthalocyanines: Synthesis, photophysical properties and photoinduced intramolecular energy transfer [J].

Chen, Jianling ;

Ye, Qing ;

Yu, Xinxin ;

Chen, Xiuqin ;

Guo, Qiumei ;

Li, Xia ;

Yang, Hongqin ;

Xie, Shusen ;

Peng, Yiru .

JOURNAL OF LUMINESCENCE, 2018, 203 :299-304

[5] High hole mobility and light-harvesting in discotic nematic dendrimers prepared via "click' chemistry [J].

Concellon, Alberto ;

Termine, Roberto ;

Golemme, Attilio ;

Romero, Pilar ;

Marcos, Mercedes ;

Luis Serrano, Jose .

JOURNAL OF MATERIALS CHEMISTRY C, 2019, 7 (10) :2911-2918

[6] Optical Properties of Vibronically Coupled Cy3 Dimers on DNA Scaffolds [J].

Cunningham, Paul D. ;

Kim, Young C. ;

Diaz, Sebastian A. ;

Buckhout-White, Susan ;

Mathur, Divita ;

Medintz, Igor L. ;

Melinger, Joseph S. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2018, 122 (19) :5020-5029

[7] ELECTRON-TRANSFER DISTANCE IN INTERMOLECULAR DIFFUSION-LIMITED REACTIONS [J].

DUTT, GB ;

PERIASAMY, N .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (24) :3815-3820

[8] Are fluorescence quantum yields so tricky to measure? A demonstration using familiar stationery products [J].

Fery-Forgues, S ;

Lavabre, D .

JOURNAL OF CHEMICAL EDUCATION, 1999, 76 (09) :1260-1264

[9] Encapsulation of phthalocyanines in biodegradable poly(sebacic anhydride) nanoparticles [J].

Fu, J ;

Li, X ;

Ng, DKP ;

Wu, C .

LANGMUIR, 2002, 18 (10) :3843-3847

[10] Morpholinyl dendrimer phthalocyanine: synthesis, photophysical properties and photoinduced intramolecular electron transfer [J].

Guo, Qiumei ;

Chen, Limin ;

Pan, Sujuan ;

Ma, Dongdong ;

Liu, Xiwen ;

Chen, Xiuqin ;

Xu, Guoxing ;

Yang, Hongqin ;

Peng, Yiru .

DALTON TRANSACTIONS, 2018, 47 (37) :13164-13170

← 1 2 3 4 →