Gaseous Cl3+ and Cl2F+ cations.: A joint mass spectrometric and theoretical study

被引：0
|
作者：
Cacace, F
de Petris, G
Pepi, F
Rosi, M
Sgamellotti, A
机构：
[1] Univ Rome La Sapienza, Dipartimento Studi Chim & Tecnol Sostanze Biologi, I-00185 Rome, Italy
[2] Univ Perugia, Dipartimento Chim, I-06100 Perugia, Italy
来源：
RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1998年 / 12卷 / 23期
关键词：
D O I：
10.1002/(SICI)1097-0231(19981215)12:23<1911::AID-RCM398>3.0.CO;2-2
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
The Cl-3(+) cation was obtained by chlorine chemical ionization (Cl-2/Cl) via the exothermic reaction of Cl+ transfer from Cl2H+ to chlorine or by the endothermic reaction of Cl-2(+.) with chlorine, whereas Cl2F+ was obtained from the reaction of XeF+ with chlorine. Both cations were structurally and energetically characterized by Fourier transform ion cyclotron resonance mass spectrometry and theoretical calculations at the B3LYP/6-311++G(3df,3pd)// CCSD(T)/cc-pVQZ levels of theory. (C) 1998 John Wiley & Sons, Ltd.
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页码：1911 / 1913
页数：3
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