Spectroscopic evaluation of Co(II), Ni(II) and Cu(II) complexes derived from thiosemicarbazone and semicarbazone

被引：24

作者：

Chandra, Sulekh ^{[1
]}

Kumar, Anil ^{[1
]}

机构：

[1] Zakir Husain Coll, Dept Chem, New Delhi 110002, India

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2007年 / 68卷 / 05期

关键词：

Co(II); Ni(II); Cu(II); spectroscopic studies;

D O I：

10.1016/j.saa.2006.12.079

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Co(II), Ni(II) and Cu(II) complexes were synthesized with thiosemicarbazone (L-1) and semicarbazone (L-2) derived from 2-acetyl furan. These complexes were characterized by elemental analysis, molar conductance, magnetic moment, mass, IR, electronic and EPR spectral studies. The molar conductance measurement of the complexes in DMSO corresponds to non-electrolytic nature. All the complexes are of high-spin type. On the basis of different spectral studies six coordinated geometry may be assigned for all the complexes except Co(L)(2)(SO4) and Cu(L)(2)(SO4) [where L=L-1 and L-2] which are of five coordinated square pyramidal geometry. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：1410 / 1415

页数：6

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