Bis[3-hydroxy-4-methyl-2(3H)-thiazolethiolato-S2,O]-bis(methanol-O)cobalt(II)

被引：3

作者：

Bond, AD ^{[1
]}

Jones, W ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801003737

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, [Co(C4H4NOS2)(2)(CH4O)(2)], has been determined at 180 (2) K. The molecule possesses (1) over bar point symmetry with the Co-II atom adopting a Jahn-Teller-distorted octahedral geometry. The molecules are linked into chains by O-H . . .O hydrogen-bond interactions involving the H atom of the coordinated methanol molecules.

引用

页码：m140 / m142

页数：3

共 11 条

[1] Albert A, 1973, SELECTIVE TOXICITY P, P130
[2] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[3] [Anonymous], 1996, CAMERON
[4] Bond AD, 2000, J PHYS ORG CHEM, V13, P395, DOI 10.1002/1099-1395(200007)13:7<395::AID-POC279>3.0.CO
[5] 2-M
[6] COBALT COMPLEXES WITH PNICOGEN (PHOSPHINE OR PYRIDINE) AND THIOLATO LIGANDS - SYNTHESES, X-RAY CRYSTAL-STRUCTURES AND SPECTROSCOPIC CHARACTERIZATION
KANG, BS
XU, YJ
PENG, JH
WU, DX
CHEN, XT
HU, YH
HONG, MC
LU, JX
[J]. POLYHEDRON, 1993, 12 (08) : 871 - 878
[7] Nonius, 1998, COLLECT
[8] Processing of X-ray diffraction data collected in oscillation mode
Otwinowski, Z
Minor, W
[J]. MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 : 307 - 326
[9] Paulus W, 1993, MICROBICIDES PROTECT, DOI DOI 10.1007/978-94-011-2118-7
[10] Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination

← 1 2 →