Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)cadmium

被引：5
|
作者：
Warad, Ismail [2 ,3 ]
Boshaala, Ahmed [2 ]
Al-Resayes, Saud I. [2 ]
Al-Deyab, Salem S. [4 ]
Rzaigui, Mohamed [1 ]
机构：
[1] Fac Sci Bizerte, Lab Chim Mat, Zarzouna 702132, Tunisia
[2] King Saud Univ, Dept Chem, Riyadh 11451, Saudi Arabia
[3] AN Najah Natl Univ, Dept Chem, Nablus, Palestinian Ter, Saudi Arabia
[4] King Saud Univ, Coll Sci, Petrochem Res Chair, Riyadh, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 43.2; mean σ(C-C) = 0.008 Å; R factor = 0.063; single-crystal X-ray study; T = 293 K; wR factor = 0.177;
D O I：
10.1107/S1600536811050069
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [CdBr2(C14H12N2)], the Cd-II ion is tetracoordinated by two N atoms of the bidentate 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions in a substantially distorted CdN2Br2 tetrahedral geometry. In the crystal, inversion dimers linked by pairs of weak C-H center dot center dot center dot Br bonds generate R-2(2)(14) loops. Aromatic pi-pi stacking [shortest centroid-centroid separation = 3.633 (2) angstrom] interactions occur within, and also link, the dimers into chains propagating parallel to [100].
引用
收藏
页码：M1846 / U361
页数：11
相关论文
共 50 条
  • [21] Dibromido(2,3-di-2-pyridylpyrazine-κ2N2,N3)palladium(II)
    Ha, Kwang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1896 - U1781
  • [22] fac-[1,2-Bis(pyridin-4-yl)ethane-kappa N]tricarbonyl(1,10-phenanthroline- kappa N-2,N')rhenium(I) hexafluoridophosphate acetonitrile monosolvate
    Guilardi, Silvana
    Toledo Patrocinio, Antonio Otavio
    de Sousa, Sinval Fernandes
    Ellena, Javier
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M278 - +
  • [23] Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-furan-2-carboxylato-κ2O:O′)cadmium(II)]
    Chen, Man-Sheng
    Zhang, Chun-Hua
    Kuang, Dai-Zhi
    Feng, Yong-Lan
    Deng, Yi-Fang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1290 - M1291
  • [24] Poly[pentakis(μ-cyanido-κ2N:C)tris(5-phenyl-2,2′-bipyridine-κ2N,N′)pentacopper(I)]
    Cui, Shuxin
    Zuo, Minghui
    Zhang, Jingping
    Zhao, Yulong
    Tan, Rongxin
    Liu, Shujuan
    Su, Shuangyue
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1706 - U1134
  • [25] catena-Poly[[(5-phenyl-2,2′-bipyridine-κ2N,N′)copper(I)]-μ-thiocyanido-κ2N:S]
    Cui, Shuxin
    Zuo, Minghui
    Zhang, Jingping
    Zhao, Yulong
    Wang, Hui
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M165 - U804
  • [26] Tris(2,2′-bipyridyl-κ2N,N′)nickel(II) β-octamolybdate tetrahydrate
    Su, Zhan-Hua
    Zhou, Bai-Bin
    Zhao, Zhi-Feng
    Zhang, Yu-Nan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1206 - M1207
  • [27] {N′,N"-Bis[2,6-bis(1-methylethyl)phenyl]-N,N-dimethylguanidinato-κ2N′,N"}dibromidoborane
    Braunschweig, Holger
    Dewhurst, Rian D.
    Schwab, Katrin
    Wagner, Katharina
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O610 - U4954
  • [28] Chlorido[1-(pyridin-2-yl)ethanone oximato-κ2N,N′][1-(2-pyridyl)ethanone oxime-κ2N,N′]copper(II) trihydrate
    Qiu, Xiumin
    Li, Leilei
    Li, Dacheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1810 - U873
  • [29] catena-Poly[[(diiodidocadmium)-μ{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κ2N:N′}] N,N-dimethyl-formamide monosolvate]
    Liu, Bingtao
    Zhao, Lei
    Li, Ting
    Meng, Xiangru
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1901 - U1283
  • [30] Bis(1,10-phenanthroline-kappa N-2, N')(sulfatoO) copper(II) propane-1,3-diol monosolvate
    Zhong, Kai-Long
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1555 - +
12345