Novel synthetic usage of indium compounds as catalyst:: Reductive deoxygenation of aryl ketones and sec-benzylic alcohols

被引：0

作者：

Miyai, T ^{[1
]}

Ueba, M ^{[1
]}

Baba, A ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 5650871, Japan

来源：

SYNLETT | 1999年 / 02期

关键词：

reductive deoxygenation; indium catalyst; chlorodimethylsilane; aromatic ketones; chemoselective reduction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of chlorodimethylsilane and a catalytic amount of indium compounds is effective for the deoxygenation of aryl ketones and sec-benzylic alcohols to the corresponding hydrocarbons. The combination system is so selective toward carbonyls that the functionalities such as halogen, ester, and ether tolerate the reduction conditions.

引用

页码：182 / 184

页数：3

共 36 条

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