A novel biomass-based polymer prepared from lignin-derived stable metabolic intermediate by copper(I)-catalyzed azide-alkyne click reaction

被引：25

作者：

Michinobu, Tsuyoshi ^{[1
,2
]}

Inazawa, Yasunori ^{[1
]}

Hiraki, Kenta ^{[1
]}

Katayama, Yoshihiro ^{[3
]}

Masai, Eiji ^{[4
]}

Nakamura, Masaya ^{[5
]}

Ohara, Seiji ^{[5
]}

Shigehara, Kiyotaka ^{[1
,2
]}

机构：

[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Koganei, Tokyo 1848588, Japan

[2] Tokyo Univ Agr & Technol, Inst Symbiot Sci & Technol, Koganei, Tokyo 1848588, Japan

[3] Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, Koganei, Tokyo 1848588, Japan

[4] Nagaoka Univ Technol, Dept Bioengn, Nagaoka, Niigata 9402188, Japan

[5] Forestry & Forest Prod Res Inst, Tsukuba, Ibaraki 3058687, Japan

来源：

CHEMISTRY LETTERS | 2008年 / 37卷 / 02期

关键词：

D O I：

10.1246/cl.2008.154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Cu-I-catalyzed, but ligand-free azide-alkyne cycloaddition reaction was applied to the polymerization of the newly synthesized diethynyl-functionalized 2-pyrone monomer originally isolated from lignin via metabolic pathway. The polymerization was monitored by GPC and IR spectra and the resulting high molecular weight polymer was unambiguously characterized by (HNMR)-H-1, thermal analysis, and optical absorption and emission spectra.

引用

页码：154 / 155

页数：2

共 19 条

[1] 'Click' chemistry in polymer and materials science [J].

Binder, Wolfgang H. ;

Sachsenhofer, Robert .

MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (01) :15-54

[2] Comparative study of inhibition effects of benzotriazole for metals in neutral solutions as observed with surface-enhanced Raman spectroscopy [J].

Cao, PG ;

Yao, JL ;

Zheng, JW ;

Gu, RA ;

Tian, ZQ .

LANGMUIR, 2002, 18 (01) :100-104

[3] Click chemistry in materials synthesis.: 1.: Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition [J].

Díaz, DD ;

Punna, S ;

Holzer, P ;

Mcpherson, AK ;

Sharpless, KB ;

Fokin, VV ;

Finn, MG .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (17) :4392-4403

[4] Catalyst performance in "click" coupling reactions of polymers prepared by ATRP: Ligand and metal effects [J].

Golas, Patricia L. ;

Tsarevsky, Nicolay V. ;

Sumerlin, Brent S. ;

Matyjaszewski, Krzysztof .

MACROMOLECULES, 2006, 39 (19) :6451-6457

[5]

KERSTEN PJ, 1982, J BACTERIOL, V152, P1154

[6]

Kolb HC, 2001, ANGEW CHEM INT EDIT, V40, P2004, DOI 10.1002/1521-3773(20010601)40:11<2004::AID-ANIE2004>3.0.CO

[7]

2-5

[8] Click chemistry in materials synthesis. III. Metal-adhesive polymers from Cu(I)-catalyzed azide-alkyne cycloaddition [J].

Liu, Yi ;

Diaz, David D. ;

Accurso, Adrian A. ;

Sharpless, K. Barry ;

Fokin, Valery V. ;

Finn, M. G. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (22) :5182-5189

[9] 1,3-dipolar cycloadditions of azides and alkynes: A universal ligation tool in polymer and materials science [J].

Lutz, Jean-Francois .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (07) :1018-1025

[10]

MICHINOBU T, POLYM J

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