Tunable absorption and emission wavelength in conjugated microporous polymers by copolymerization

被引：50

作者：

Brandt, Jessica ^{[1
]}

Schmidt, Johannes ^{[2
]}

Thomas, Arne ^{[2
]}

Epping, Jan Dirk ^{[2
]}

Weber, Jens ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany

[2] Tech Univ Berlin, Dept Chem, D-10587 Berlin, Germany

来源：

POLYMER CHEMISTRY | 2011年 / 2卷 / 09期

关键词：

INTRINSIC MICROPOROSITY; SURFACE-AREA; GAS SORPTION; NETWORKS; SPIROBIFLUORENE;

D O I：

10.1039/c1py00217a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Conjugated, microporous polymers based on a spirobifluorene core were synthesized by Suzuki polycondensation of the tetra-bromospirobifluorene with benzene diboronic acid and/or thiophene diboronic acid. The optical properties (absorption and emission spectra) and the gas sorption properties (N(2) and CO(2)) are analyzed and discussed.

引用

页码：1950 / 1952

页数：3

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