High performance supercapacitors based on highly conductive nitrogen-doped graphene sheets

被引:276
作者
Qiu, Yongcai [1 ]
Zhang, Xinfeng [1 ]
Yang, Shihe [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Nano Sci & Technol Program, Dept Chem, William Mong Inst Nano Sci & Technol, Kowloon, Hong Kong, Peoples R China
关键词
ELECTROCHEMICAL CAPACITORS; ACTIVATED CARBON; ENERGY-STORAGE; GRAPHITE OXIDE; ULTRACAPACITORS; REDUCTION; BATTERIES; ELECTRODE;
D O I
10.1039/c1cp21148j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermal nitridation of reduced graphene oxide sheets yields highly conductive (similar to 1000-3000 S m(-1)) N-doped graphene sheets, as a result of the restoration of the graphene network by the formation of C-N bonded groups and N-doping. Even without carbon additives, supercapacitors made of the N-doped graphene electrodes can deliver remarkable energy and power when operated at higher voltages, in the range of 0-4 V.
引用
收藏
页码:12554 / 12558
页数:5
相关论文
共 38 条
[1]  
[Anonymous], 1999, ELECTROCHEMICAL SUPE
[2]   Ultracapacitors: why, how, and where is the technology [J].
Burke, A .
JOURNAL OF POWER SOURCES, 2000, 91 (01) :37-50
[3]   Polyaniline-deposited porous carbon electrode for supercapacitor [J].
Chen, WC ;
Wen, TC ;
Teng, HS .
ELECTROCHIMICA ACTA, 2003, 48 (06) :641-649
[4]   A Three-Dimensional Carbon Nanotube/Graphene Sandwich and Its Application as Electrode in Supercapacitors [J].
Fan, Zhuangjun ;
Yan, Jun ;
Zhi, Linjie ;
Zhang, Qiang ;
Wei, Tong ;
Feng, Jing ;
Zhang, Milin ;
Qian, Weizhong ;
Wei, Fei .
ADVANCED MATERIALS, 2010, 22 (33) :3723-+
[5]  
Gao W, 2009, NAT CHEM, V1, P403, DOI [10.1038/NCHEM.281, 10.1038/nchem.281]
[6]   Energy storage in electrochemical capacitors: designing functional materials to improve performance [J].
Hall, Peter J. ;
Mirzaeian, Mojtaba ;
Fletcher, S. Isobel ;
Sillars, Fiona B. ;
Rennie, Anthony J. R. ;
Shitta-Bey, Gbolahan O. ;
Wilson, Grant ;
Cruden, Andrew ;
Carter, Rebecca .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (09) :1238-1251
[7]   STUDY OF OXYGEN-CONTAINING GROUPS IN A SERIES OF GRAPHITE OXIDES - PHYSICAL AND CHEMICAL CHARACTERIZATION [J].
HONTORIALUCAS, C ;
LOPEZPEINADO, AJ ;
LOPEZGONZALEZ, JDD ;
ROJASCERVANTES, ML ;
MARTINARANDA, RM .
CARBON, 1995, 33 (11) :1585-1592
[8]   Influence of oxygen treatment on electric double-layer capacitance of activated carbon fabrics [J].
Hsieh, CT ;
Teng, H .
CARBON, 2002, 40 (05) :667-674
[9]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[10]   Principles and applications of electrochemical capacitors [J].
Kötz, R ;
Carlen, M .
ELECTROCHIMICA ACTA, 2000, 45 (15-16) :2483-2498