Electrodeposited lead dioxide coatings

被引:324
作者
Li, Xiaohong [1 ]
Pletcher, Derek [2 ]
Walsh, Frank C. [1 ]
机构
[1] Univ Southampton, Sch Engn Sci, Electrochem Engn Lab, Southampton SO17 1BJ, Hants, England
[2] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
关键词
OXYGEN-TRANSFER REACTIONS; GLASSY-CARBON ELECTRODES; BORON-DOPED DIAMOND; ASSISTED PHOTOCATALYTIC DEGRADATION; MODEL ORGANIC SUBSTRATE; WASTE-WATER TREATMENT; ELECTROCHEMICAL DEGRADATION; ANODIC-OXIDATION; SOLUBLE LEAD(II); FLOW BATTERY;
D O I
10.1039/c0cs00213e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lead dioxide coatings on inert substrates such as titanium and carbon now offer new opportunities for a material known for 150 years. It is now recognised that electrodeposition allows the preparation of stable coatings with different phase structures and a wide range of surface morphologies. In addition, substantial modification to the physical properties and catalytic activities of the coatings are possible through doping and the fabrication of nanostructured deposits or composites. In addition to applications as a cheap anode material in electrochemical technology, lead dioxide coatings provide unique possibilities for probing the dependence of catalytic activity on layer composition and structure (critical review, 256 references).
引用
收藏
页码:3879 / 3894
页数:16
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