A highly symmetric diamond-like assembly of cyclotricatechylene-based tetrahedral cages

被引：28

作者：

Abrahams, Brendan F. ^{[1
]}

Boughton, Berin A. ^{[2
]}

FitzGerald, Nicholas J. ^{[1
]}

Holmes, Jessica L. ^{[1
]}

Robson, Richard ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

[2] Univ Melbourne, Sch Bot, Melbourne, Vic 3010, Australia

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 26期

关键词：

CATIONIC RUTHENIUM COMPLEXES; LIGANDS; BEHAVIOR;

D O I：

10.1039/c1cc12723c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of six Cu(II) centres with four cyclotricatechylene (ctc(6-)) ligands generates large (Cu(6)ctc(4))(12-) cages with the topology of the tetrahedron. The anionic tetrahedral cages are cemented together, triangular face to triangular face, by Na+ cations together with water molecules to generate a highly symmetric diamond-like assembly (space group Fd-3m, the same as that of diamond itself) whose adamantane-like units have an iodide ion at the centre of every cyclohexane-like face.

引用

页码：7404 / 7406

页数：3

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