Ru-catalyzed hydrogenolysis of chiral allylic and propargylic cyclic carbonates: Synthesis of optically active (E)-allylic and allenic alcohols

被引：5
|
作者：
Kang, SK
Kim, DY
Rho, HS
Yoon, SH
Ho, PS
机构：
[1] Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus
来源：
SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 08期
关键词：
D O I：
10.1080/00397919608003514
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
RuH2(PP3)(4)-catalyzed reductive cleavage reactions of chiral allylic cyclic carbonates with ammonium formate afforded optically active (E)-allylic alcohols with excellent regioselectivity. Alternatively, hydrogenolysis of propargylic cyclic carbonates in the presence of RuH2(PPh(3))(4) catalyst afforded allenic alcohols as a sole products.
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页码：1485 / 1492
页数：8
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