A new strategy to exfoliate silicone rubber/clay nanocomposites

被引：63

作者：

Ma, J ^{[1
]}

Yu, ZZ ^{[1
]}

Kuan, HC ^{[1
]}

Dasari, A ^{[1
]}

Mai, YW ^{[1
]}

机构：

[1] Univ Sydney, Sch Aerosp Mech & Mechatron Engn J07, Ctr Adv Mat Technol, Sydney, NSW 2006, Australia

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 10期

关键词：

clay; exfoliation; nanocomposites; silicone rubber;

D O I：

10.1002/marc.200500007

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new strategy was developed to prepare disorderly exfoliated nanocomposites, in which a soft siloxane surfactant with a weight-average molecular weight (H,,) of 1900 was adopted to modify the clay. The modified clay slurry was then mixed with silicone rubber by hand, and exfoliation was achieved. The proposed mechanism thereof was verified by TEM and XRD. The physical entanglement of the soft siloxane surfactant plays a vital role in the diffusion and intercalation of the matrix molecules during the compounding of the slurry-polymer mixture. This simple method is applicable to other silicone-based materials reinforced by clay.

引用

页码：830 / 833

页数：4

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