Defect-Engineered Graphene for High-Energy- and High-Power-Density Supercapacitor Devices

被引:258
作者
Zhu, Jingyi [1 ]
Childress, Anthony S. [1 ]
Karakaya, Mehmet [1 ]
Dandeliya, Sushmita [2 ]
Srivastava, Anurag [2 ]
Lin, Ye [3 ]
Rao, Apparao M. [1 ]
Podila, Ramakrishna [1 ,4 ]
机构
[1] Clemson Univ, Dept Phys & Astron, Clemson Nanomat Ctr, COMSET, Clemson, SC 29634 USA
[2] ABV Indian Inst Informat Technol & Management, Gwalior 474010, Madhya Pradesh, India
[3] Univ South Carolina, Dept Chem Engn, Columbia, SC 29208 USA
[4] Clemson Univ, Lab Nanobiophys, Clemson, SC 29634 USA
基金
美国国家科学基金会;
关键词
IONIC LIQUID; CARBON; CAPACITANCE; SIZE;
D O I
10.1002/adma.201602028
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Defects are often written off as performance limiters. Contrary to this notion, it is shown that controlling the defect confi guration in graphene is critical to overcome a fundamental limitation posed by quantum capacitance and opens new channels for ion diffusion. Defect-engineered graphene flexible pouch capacitors with energy densities of 500% higher than the state-of-the-art supercapacitors are demonstrated.
引用
收藏
页码:7185 / +
页数:9
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