Synthesis and crystal structure of [Li(NH3)4]4[Sn9]•NH3 and [Li(NH3)4]4[Pb9]•NH3

被引：33

作者：

Korber, N ^{[1
]}

Fleischmann, A ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93053 Regensburg, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 04期

关键词：

D O I：

10.1039/b008123j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of an excess of Sn or Pb with a concentrated solution of Li in liquid ammonia yielded black crystals of [Li(NH3)(4)](4)[Sn-9]. NH3 or [Li(NH3)(4)](4)[Pb-9]. NH3 as main product, respectively. The compounds are isotypic and crystallise in space group P2(1)/c. They contain the isolated Zintl anions Sn-9(4-) and Pb-9(4-), which form slightly distorted monocapped square antiprisms. The lead compound is the first example of a "naked" Pb-9(4-) cage without contacts to metal atoms.

引用

页码：383 / 385

页数：3

共 50 条

[31] NH4VO(NH3)PO4 [J].

Fratzky, D ;

Worzala, H ;

Goetze, T ;

Meisel, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 :156-157

[32] OPTICAL-PROPERTIES OF CONCENTRATED LI-NH3 SOLUTIONS AND SOLID LI(NH3)4 [J].

MCKNIGHT, WH ;

THOMPSON, JC .

JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (26) :2984-2986

[33] Electronic structure and stability of NH4(NH3)(n) and NH4(NH3)(m)(H2O)(n) [J].

Takasu, R ;

Fuke, K ;

Misaizu, F .

SURFACE REVIEW AND LETTERS, 1996, 3 (01) :353-357

[34] Phase transition and dynamics of NH3 ligands in [Zn(NH3)4](ReO4)2 [J].

Hetmanczyk, Lukasz ;

Hetmanczyk, Joanna .

VIBRATIONAL SPECTROSCOPY, 2016, 86 :40-49

[35] POLARIZED CRYSTAL SPECTRA OF NI(NH3)4)NCS)2 + NI)NH3)4)NO2)2 [J].

HARE, CR ;

BALLHAUSEN, CJ .

JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (03) :792-&

[36] Crystal structure of {[Pd(NH3)4]3[Pd(NH3)3Cl]2}Cl8 [J].

Gromilov, SA ;

Baidina, IA ;

Tatarchuk, VV ;

Virovets, AV ;

Druzhinina, IA .

JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 40 (04) :629-632

[37] Crystal structure of [Pd(NH3)4]3[Pd(NH3)3Cl]2 Cl8 [J].

S. A. Gromilov ;

I. A. Baidina ;

V. V. Tatarchuk ;

A. V. Virovets ;

I. A. Druzhinina .

Journal of Structural Chemistry, 1999, 40 :629-632

[38] SYNTHESIS OF TRANS[CR(NH3)4(NCS)2]+, TRANS[CR(NH3)4NCSF]+ AND [CR(NH3)5NCS]2+ [J].

KIRK, AD ;

WONG, CFC .

INORGANICA CHIMICA ACTA, 1978, 27 (02) :265-267

[39] Synthesis and crystal structure of the fluoride-ammine complexes Zr(NH3)F-4 and Hf(NH3)F-4 [J].

Plitzko, C ;

Strecker, M ;

Meyer, G .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (01) :79-83

[40] CRYSTAL STRUCTURE OF (ZN(NH3)4)(OSO3N)2 AND (CD(NH3)4)(OSO3N)2 [J].

MULLER, A ;

BOSCHEN, I ;

SIEVERT, W .

ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1970, B 25 (03) :311-&

← 1 2 3 4 5 →