Synthesis and crystal structure of [Li(NH3)4]4[Sn9]•NH3 and [Li(NH3)4]4[Pb9]•NH3

被引：33

作者：

Korber, N ^{[1
]}

Fleischmann, A ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93053 Regensburg, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 04期

关键词：

D O I：

10.1039/b008123j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of an excess of Sn or Pb with a concentrated solution of Li in liquid ammonia yielded black crystals of [Li(NH3)(4)](4)[Sn-9]. NH3 or [Li(NH3)(4)](4)[Pb-9]. NH3 as main product, respectively. The compounds are isotypic and crystallise in space group P2(1)/c. They contain the isolated Zintl anions Sn-9(4-) and Pb-9(4-), which form slightly distorted monocapped square antiprisms. The lead compound is the first example of a "naked" Pb-9(4-) cage without contacts to metal atoms.

引用

页码：383 / 385

页数：3

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