Synthesis, formation mechanism and sensing properties of WO3 hydrate nanowire netted-spheres

被引:42
作者
Yan, Aihua [1 ]
Xie, Changsheng [1 ,2 ]
Zeng, Dawen [1 ]
Cai, Shuizhou [2 ]
Hu, Mulin [2 ]
机构
[1] Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China
[2] Huazhong Univ Sci & Technol, Dept Mat Sci & Engn, Nanomat & Smart Sensor Res Lab, Wuhan 430074, Peoples R China
关键词
Nanostructure; Surface; Chemical synthesis; Semiconductivity; TUNGSTEN-OXIDE NANOWIRES; ELECTROCHROMIC PROPERTIES; THIN-FILMS; NANORODS; NANOSTRUCTURES; WCL6;
D O I
10.1016/j.materresbull.2010.05.026
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Tungsten oxide hydrate nanowire netted-spheres were successfully synthesized in the glycol solution using a facile solvothermal approach. The nanowires with uniform diameter of 4-6 nm are actually a kind of tungsten oxide hydrate/surfactant hybrid materials. The influence of surfactant, solvent, time and temperature on tailoring morphology was investigated in detail. The possible formation process of WO3 hydrate nanowire netted-sphere was proposed. Sensing properties of such WO3 hydrate sensor show that the desirable sensing characteristics towards 100 ppm ammonia gas at 320 degrees C were obtained, such as rapid response (18.3 s), high sensitivity, good reproducibility and stability. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1541 / 1547
页数:7
相关论文
共 21 条
  • [1] The APCVD of tungsten oxide thin films from reaction of WCl6 with ethanol and results on their gas-sensing properties
    Ashraf, Sobia
    Binions, Russell
    Blackman, Christopher S.
    Parkin, Ivan P.
    [J]. POLYHEDRON, 2007, 26 (07) : 1493 - 1498
  • [2] Atmospheric pressure chemical vapor deposition of crystalline monoclinic WO3 and WO3-x thin films from reaction of WCl6 with O-containing solvents and their photochromic and electrochromic properties
    Blackman, CS
    Parkin, IP
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (06) : 1583 - 1590
  • [3] Solvothermal synthesis of tungsten oxide nanorod/nanowire/nanosheet
    Choi, HG
    Jung, YH
    Kim, DK
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (06) : 1684 - 1686
  • [4] Low temperature synthesis of nanocrystalline WO3 films by sol-gel process
    Djaoued, Y.
    Priya, S.
    Balaji, S.
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (2-9) : 673 - 679
  • [5] Biotemplated synthesis of single-crystalline W18O49@C core-shell nanorod and its capacitance properties
    Ganesan, Raman
    Perelshtein, Ilana
    Gedanken, Aharon
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (06) : 1913 - 1919
  • [6] Synthesis and optical properties of colloidal tungsten oxide nanorods
    Lee, K
    Seo, WS
    Park, JT
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) : 3408 - 3409
  • [7] Highly sensitive WO3 hollow-sphere gas sensors
    Li, XL
    Lou, TJ
    Sun, XM
    Li, YD
    [J]. INORGANIC CHEMISTRY, 2004, 43 (17) : 5442 - 5449
  • [8] Large-scale synthesis of tungsten oxide nanowires with high aspect ratio
    Li, XL
    Liu, JF
    Li, YD
    [J]. INORGANIC CHEMISTRY, 2003, 42 (03) : 921 - 924
  • [9] Tuning the field-emission properties of tungsten oxide nanorods
    Liu, JG
    Zhang, ZJ
    Zhao, Y
    Su, X
    Liu, S
    Wang, EG
    [J]. SMALL, 2005, 1 (03) : 310 - 313
  • [10] Synthesis, Mechanism, and Gas-Sensing Application of Surfactant Tailored Tungsten Oxide Nanostructures
    Pokhrel, Suman
    Simion, Cristian E.
    Teodorescu, Valentin S.
    Barsan, Nicolae
    Weimar, Udo
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (11) : 1767 - 1774