Room-temperature ferromagnetism and ferroelectricity of nanocrystalline La2Ti2O7

被引:34
作者
Sun, Li [1 ]
Hu, Jifan [1 ]
Gao, Feng [1 ]
Kong, Xiangwei [1 ]
Qin, Hongwei [1 ]
Jiang, Minhua [1 ]
机构
[1] Shandong Univ, Sch Phys, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanocrystalline; Multiferroic material; Ferromagnetism; Ferroelectricity; POLARIZATION; MAGNETISM; OXIDE;
D O I
10.1016/j.jallcom.2010.04.137
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
La2Ti2O7 nanocrystalline powders and pellets were prepared by sol-gel method. The nanocrystalline powders present room-temperature ferromagnetism (FM). The vacuum annealing enhances FM, showing that the observed room-temperature FM for La2Ti2O7 possibly originates from oxygen vacancies at/near surfaces of nanograins. La2Ti2O7 pellets annealed at 1000 degrees C for 1 h show the coexistence of ferromagnetism and ferroelectricity (FE) at room temperature. Meanwhile, the room-temperature magnetodielectric (MD) effect was also observed in the La2Ti2O7 multiferroic pellet, indicating the coupling between magnetic and electric properties. The value of Delta epsilon(r)/epsilon(r)(0) for La2Ti2O7 multiferroic pellet reaches 39.3% at 1 kHz under H = 6 kOe. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:176 / 179
页数:4
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