Solvothermal synthesis of CuS/Cu(OH)2 nanocomposite electrode materials for supercapacitor applications

被引:37
作者
Naveenkumar, Perumal [1 ]
Kalaignan, Guruviah Paruthimal [1 ]
Arulmani, Subramanian [2 ]
Anandan, Sambandam [2 ]
机构
[1] Alagappa Univ, Dept Ind Chem, Mat Res Lab, Karaikkudi 630 003, Tamil Nadu, India
[2] Natl Inst Technol, Dept Chem, Nanomat & Solar Energy Convers Lab, Tiruchirappalli 620 015, India
关键词
CHEMICAL-SYNTHESIS; CARBON NANOTUBES; HIERARCHICAL CUS; FACILE SYNTHESIS; THIN-FILMS; PERFORMANCE; CU(OH)(2); ARRAYS; HYDROXIDE; MICROSPHERES;
D O I
10.1007/s10854-018-9780-y
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this work, we have synthesized the CuS/Cu(OH)(2) nanocomposite electrode materials by the simple solvothermal method. The crystal structure, phase purity and the presence of functional groups in the metal sulfide/ hydroxide are confirmed by XRD and FTIR techniques. The SEM images of nanocomposite have sphere like morphology with small agglomerations. Electrochemical results show the high specific capacitance of CuS/Cu(OH)(2) composite is 845.5 F/g (capacity of 93.9 mAh/g) which is higher than that of individuals of Cu(OH)(2)-419.7 F/g (capacity of 46.6 mAh/g) and CuS-738.3 F/g (capacity of 82 mAh/g) at a fixed current density of 1 mA/cm(2). Further, the composite gives a better result as in the form of capacitance retention (78.6%) over 1000 continuous charge-discharge cycles. Consequently, the results suggest that CuS/Cu(OH)(2) nanocomposite can be used as a promising electrode material for supercapacitor applications.
引用
收藏
页码:16853 / 16863
页数:11
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