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Solvothermal synthesis of CuS/Cu(OH)2 nanocomposite electrode materials for supercapacitor applications
被引:37
作者:
Naveenkumar, Perumal
[1
]
Kalaignan, Guruviah Paruthimal
[1
]
Arulmani, Subramanian
[2
]
Anandan, Sambandam
[2
]
机构:
[1] Alagappa Univ, Dept Ind Chem, Mat Res Lab, Karaikkudi 630 003, Tamil Nadu, India
[2] Natl Inst Technol, Dept Chem, Nanomat & Solar Energy Convers Lab, Tiruchirappalli 620 015, India
关键词:
CHEMICAL-SYNTHESIS;
CARBON NANOTUBES;
HIERARCHICAL CUS;
FACILE SYNTHESIS;
THIN-FILMS;
PERFORMANCE;
CU(OH)(2);
ARRAYS;
HYDROXIDE;
MICROSPHERES;
D O I:
10.1007/s10854-018-9780-y
中图分类号:
TM [电工技术];
TN [电子技术、通信技术];
学科分类号:
0808 ;
0809 ;
摘要:
In this work, we have synthesized the CuS/Cu(OH)(2) nanocomposite electrode materials by the simple solvothermal method. The crystal structure, phase purity and the presence of functional groups in the metal sulfide/ hydroxide are confirmed by XRD and FTIR techniques. The SEM images of nanocomposite have sphere like morphology with small agglomerations. Electrochemical results show the high specific capacitance of CuS/Cu(OH)(2) composite is 845.5 F/g (capacity of 93.9 mAh/g) which is higher than that of individuals of Cu(OH)(2)-419.7 F/g (capacity of 46.6 mAh/g) and CuS-738.3 F/g (capacity of 82 mAh/g) at a fixed current density of 1 mA/cm(2). Further, the composite gives a better result as in the form of capacitance retention (78.6%) over 1000 continuous charge-discharge cycles. Consequently, the results suggest that CuS/Cu(OH)(2) nanocomposite can be used as a promising electrode material for supercapacitor applications.
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页码:16853 / 16863
页数:11
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