Two Novel Crystal Structures of 2-Mercapto-1,3,4-thiadiazole Complexes with Mercury (II) Chloride

被引：3

作者：

Hu, Pu-Zhou ^{[1
]}

Wang, Jian-Ge ^{[1
]}

Liu, Jing ^{[1
]}

Zhao, Bang-Tun ^{[1
]}

机构：

[1] Luoyang Normal Univ, Dept Chem, Luoyang 471022, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 10期

基金：

中国国家自然科学基金;

关键词：

2-Mercapto-1,3,4-thiadiazole (MTD); Mercury (II) chloride; Single structure; Supramolecular architecture; COORDINATION; LIGANDS; HALIDE;

D O I：

10.1007/s10870-010-9747-1

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Two novel complexes 1 and 2 have been simultaneously obtained by the reaction of 2-mercapto-1,3,4- thiadiazole (MTD) with mercury (II) chloride (HgCl2) in CH3CN, and their crystal structures are characterized by single-crystal X-ray diffraction analysis. Crystal structures show that each Hg(II) of 1 is four coordinated with two chloride anions and two exocyclic sulfur atoms of two adjacent MTDs, and each Hg(II) of 2 is three coordinated with one chloride anion, one nitrogen atom and one exocyclic sulfur atom of two adjacent MTDs, respectively. Assisting the intermolecular works such as S center dot center dot center dot S, S center dot center dot center dot Cl or Hg center dot center dot center dot S interactions, both two complexes 1 and 2 are formed 2D supramolecular architectures. The results obtained conform the MTD can exist thiol and thione forms in the solid state.

引用

页码：825 / 830

页数：6

共 50 条

[1] Two Novel Crystal Structures of 2-Mercapto-1,3,4-thiadiazole Complexes with Mercury (II) Chloride
Pu-Zhou Hu
Jian-Ge Wang
Jing Liu
Bang-Tun Zhao
Journal of Chemical Crystallography, 2010, 40 : 825 - 830
[2] Syntheses and Characterization of Organotin(IV) Complexes Derived from 2-Mercapto-1,3,4-thiadiazole
Wang, Qingfeng
Ma, Chunlin
He, Guofang
Li, Yanfei
HETEROATOM CHEMISTRY, 2012, 23 (06) : 531 - 538
[3] ZINC (II), CADMIUM (II) AND MERCURY (II) COMPLEXES OF 2-METHYL-5-MERCAPTO-1,3,4-THIADIAZOLE
FABRETTI, AC
FRANCHINI, GC
PEYRONEL, G
BELLEI, M
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1981, 37 (08) : 587 - 590
[4] SIMPLE NEW ROUTES TO PHOSPHORINS FROM 2-MERCAPTO-1,3,4-OXATRIAZOLE AND 2-MERCAPTO-1,3,4-THIADIAZOLE AND 3-MERCAPTO-1,2,4-TRIAZOLE
FAHMY, AA
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 68 (1-4): : 139 - 145
[5] ZINC(II), CADMIUM(II) AND MERCURY(II) COMPLEXES WITH 2-AMINO-1,3,4-THIADIAZOLE AND 2-ETHYLAMINO-1,3,4-THIADIAZOLE
FABRETTI, AC
FRANCHINI, GC
PEYRONEL, G
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1982, 38 (02): : 175 - 179
[6] Syntheses and Crystal Structures of Two Novel Cobalt(II) Complexes with 2-Amino-5-substituted-1,3,4-thiadiazole as Ligands
An Yue
Mu Ping-Ping
Guo Zhi-Ping
Zhou Guang-Hua
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (05) : 607 - 611
[7] 1,3,4-Thiadiazole derivatives .6. Polynuclear complexes of 2-amino-5-mercapto-1,3,4-thiadiazole with Co(II) and Ni(II)
Brezeanu, M
Olar, R
Supuran, CT
Stanica, N
Stoicescu, M
REVUE ROUMAINE DE CHIMIE, 1996, 41 (9-10) : 681 - 685
[8] 1,3,4-thiadiazole derivatives .5. Heteropolynuclear complexes of 2-amino-5-mercapto-1,3,4-thiadiazole
Brezeanu, M
Olar, R
Meghea, A
Stanica, N
Supuran, CT
REVUE ROUMAINE DE CHIMIE, 1996, 41 (1-2) : 103 - 107
[9] COPPER(II) COMPLEXES OF 2-AMINO-1,3,4-THIADIAZOLE AND 2-ETHYLAMINO-1,3,4-THIADIAZOLE
FABRETTI, AC
FRANCHINI, GC
PEYRONEL, G
TRANSITION METAL CHEMISTRY, 1982, 7 (06) : 306 - 310
[10] 1,3,4-THIADIAZOLE DERIVATIVES .4. COMPLEXES OF CU(II) WITH 2-AMINO-5-MERCAPTO-1,3,4-THIADIAZOLE - A NOVEL CLASS OF CARBONIC-ANHYDRASE INHIBITORS
SUPURAN, CT
LEPADATU, CI
OLAR, R
MEGHEA, A
BREZEANU, M
REVUE ROUMAINE DE CHIMIE, 1993, 38 (12) : 1509 - 1517

← 1 2 3 4 5 →