Thermocatalytic decomposition of 1-methylcyclohexyl hydroperoxide

被引：1

作者：

Syroezhko, AM ^{[1
]}

Begak, OY

机构：

[1] St Petersburg State Technol Inst, St Petersburg, Russia

[2] Fed State Unitary Enterprise, Mendeleev Russian Res Inst Metrol, St Petersburg, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2004年 / 77卷 / 12期

关键词：

Sodium; Mathematical Model; Hydroperoxide; Equilibrium Constant; Stearate;

D O I：

10.1007/s11167-005-0204-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A mathematical model of a multistage process of thermocatalytic decomposition of 1-methylcyclohexyl hydroperoxide in the presence of sodium stearate is developed. A procedure for calculating the unknown rate and equilibrium constants of the elementary and overall reaction stages is described. It is based on an analysis of the kinetic relationships in consumption of the initial products and accumulation of the intermediate and final products of thermocatalytic decomposition, with account of the known constants for individual stages.

引用

页码：1979 / 1986

页数：8