Manganese-Based Metal-Organic Frameworks as Heterogeneous Catalysts for the Cyanosilylation of Acetaldehyde

被引：69
作者：
Ladrak, Tim [2 ]
Smulders, Simon [2 ]
Roubeau, Olivier [1 ]
Teat, Simon J. [3 ]
Gamez, Patrick [2 ]
Reedijk, Jan [2 ]
机构：
[1] CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
[2] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA 94720 USA
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 24期
关键词：
Metal-organic networks; Heterogeneous catalysis; Manganese; Lewis acids; Trigonal prisms; RAY CHARGE-DENSITY; COORDINATION POLYMERS; TRIMETHYLSILYL CYANIDE; CRYSTAL-STRUCTURE; POROUS SOLIDS; TEREPHTHALATE; PHOTOLUMINESCENCE; STABILITY; KETONES; MN(II);
D O I：
10.1002/ejic.201000378
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal-organic frameworks (MOFs), namely [Mn-3(atpa)(3)(dmf)(2)] and [Mn-2(tpa)(2)(dmf)(2)], were prepared in N,N-dimethylformamide (dmf) from manganese(II) nitrate and two dicarboxylic acid ligands, 2-aminoterephthalic acid (H(2)atpa) and terephthalic acid (H(2)tpa). The molecular structures of these MOFs are compared to two related coordination polymers, namely [Mn-3(atpa)(2)(Hatpa)(2)] and [Mn-3(tpa)(3)(-)(def)(2)], which were obtained in N,N-diethylformamide (def), to examine the effect of slight ligand or solvent changes on the framework architecture. The four Mn-based MOFs were used as effective Lewis catalysts for the cyanosilylation of acetaldehyde. The four heterogeneous catalytic systems can be re-used without any apparent loss of activity.
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收藏
页码：3804 / 3812
页数：9
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