Preparation of vicinal diimines: a new dehydrogenative coupling reaction of aldimines mediated by ytterbium metal

被引：11

作者：

Jin, WS ^{[1
]}

Makioka, Y ^{[1
]}

Taniguchi, Y ^{[1
]}

Kitamura, T ^{[1
]}

Fujiwara, Y ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Biochem & Chem, Higashi Ku, Fukuoka 8128581, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 10期

关键词：

D O I：

10.1039/a801514g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dehydrogenative coupling takes place to give vicinal diimine compounds in the reaction of aromatic aldimines with ytterbium metal followed by treatment with aromatic aldehydes such as 1-naphthaldehyde (1-NpCHO) as a hydrogen acceptor.

引用

页码：1101 / 1102

页数：2

共 17 条

[1]

DJERASSI C, 1951, ORG REACTIONS, V6, P207

[2] A ROUTE TO VICINAL DIAMINES FROM THE SAMARIUM(II) IODIDE-MEDIATED COUPLING OF ALDIMINES [J].

ENHOLM, EJ ;

FORBES, DC ;

HOLUB, DP .

SYNTHETIC COMMUNICATIONS, 1990, 20 (07) :981-987

[3] NEW SYNTHETIC REACTIONS BY MEANS OF RARE-EARTH REAGENTS [J].

FUJIWARA, Y ;

TAKAKI, K ;

TANIGUCHI, Y .

JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 192 (1-2) :200-204

[4] NOVEL CRYSTAL-STRUCTURE OF YTTERBIUM(II)-BENZOPHENONE DIANION COMPLEX AND ITS REACTION WITH 2,6-DI-TERT-BUTYL-4-METHYLPHENOL [J].

HOU, ZM ;

YAMAZAKI, H ;

KOBAYASHI, K ;

FUJIWARA, Y ;

TANIGUCHI, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (09) :722-724

[5] NUCLEOPHILIC-ADDITION OF LANTHANOID METAL UMPOLED DIARYL KETONES TO ELECTROPHILES [J].

HOU, ZM ;

TAKAMINE, K ;

AOKI, O ;

SHIRAISHI, H ;

FUJIWARA, Y ;

TANIGUCHI, H .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (26) :6077-6084

[6] SAMARIUM DIIODIDE-PROMOTED REDUCTIVE COUPLING OF IMINES [J].

IMAMOTO, T ;

NISHIMURA, S .

CHEMISTRY LETTERS, 1990, (07) :1141-1142

[7]

IMAMOTO T, 1994, LANTHANIDES ORGANIC, P7

[8]

LEBRUN A, 1995, NEW J CHEM, V19, P699

[9] YTTERBIUM METAL-MEDIATED DESULFURIZATION AND COUPLING REACTION OF DIARYL THIOKETONES [J].

MAKIOKA, Y ;

UEBORI, S ;

TSUNO, M ;

TANIGUCHI, Y ;

TAKAKI, K ;

FUJIWARA, Y .

CHEMISTRY LETTERS, 1994, (03) :611-614

[10] The first isolation and structural characterization of a lanthanoid - Imine azametallacyclopropane complex, [Yb(eta(2)-Ph(2)CNPh)(HMPA)(3)] [J].

Makioka, Y ;

Taniguchi, Y ;

Fujiwara, Y ;

Takaki, K ;

Hou, ZM ;

Wakatsuki, Y .

ORGANOMETALLICS, 1996, 15 (26) :5476-5478

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