Effect of Doping of Plant Raw-Based Activated Carbons with Iron Nanoparticles on Their Catalytic Activity in the Reaction of Propane Dehydrogenation

被引：3

作者：

Revina, A. A. ^{[1
]}

Markova, E. B. ^{[1
,2
]}

Suvorova, O. V. ^{[1
]}

Tereshina, T. A. ^{[2
]}

Cherednichenko, A. G. ^{[2
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia

[2] Peoples Friendship Univ Russia, Moscow 117198, Russia

来源：

PETROLEUM CHEMISTRY | 2020年 / 60卷 / 05期

关键词：

iron nanoparticles; reverse-micellar solutions; propane dehydrogenation; carbon sorbents based on plant raw materials; activated carbons;

D O I：

10.1134/S0965544120050096

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method is developed for creating highly active and selective catalysts for associated petroleum gas cracking which is based on use of activated carbons derived from renewable sources of plant raw materials (Jerusalem artichoke, false flax, rape, wheat) modified with nanosized iron particles obtained in reverse-micellar solutions. It is shown that carbon matrices modified with iron nanoparticles possess a high catalytic activity with the maximum conversion attained at 900 K and a high selectivity for olefin formation (about 95%).

引用

页码：585 / 591

页数：7

共 11 条

[1] Chekmar' D. V., 2015, P 2 ALL UN C INT PAR, P62
[2] Egorova E.M., 2001, Herald of Moscow University. Series 2: Chemistry, V42, P332
[3] Nanoheterogeneous catalysis: Definition, state, and research prospects (Review)
Khadzhiev, S. N.
[J]. PETROLEUM CHEMISTRY, 2016, 56 (06) : 465 - 479
[4] Electron beam agrobionanotechnologies for agriculture and food industry enabled by electron accelerators
Pavlov, Y. S.
Revina, A. A.
Souvorova, O. V.
Voropaeva, N. L.
Chekmar, D. V.
Abkhalimov, E. V.
Zavyalov, M. A.
Filippovich, V. P.
[J]. III INTERNATIONAL CONFERENCE ON LASER AND PLASMA RESEARCHES AND TECHNOLOGIES, 2018, 941
[5] Revina A. A., 2008, RF Patent, Patent No. 2322327
[6] Revina A. A., 2015, 1 INT C SCI PRACT C, P164
[7] Revina A. A., 2019, PROT MET PHYS CHEM, V55, P531, DOI [10.1134/S0044185619040168, DOI 10.1134/S0044185619040168]
[8] Revina A. A., 2010, PORT MET PHYS CHEM S, V46, P578, DOI [10.1134/S2070205110050138, DOI 10.1134/S2070205110050138]
[9] Effect of water treatment and Fe doping on Pt sintering and the propane oxidation activity of Pt/Al2O3
Tomita, Atsuko
Miki, Takeshi
Tai, Yutaka
[J]. APPLIED CATALYSIS A-GENERAL, 2016, 522 : 138 - 144
[10] Voropaeva N. L., 2015, GEOSCIENCE ENG, VLXI, P247

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