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Many-body interactions between particles in a polydisperse polymer fluid
被引:7
|作者:
Woodward, Clifford E.
[1
]
Forsman, Jan
[2
]
机构:
[1] Univ New S Wales, Univ Coll, Sch Phys Environm & Math Sci, ADFA, Canberra, ACT 2600, Australia
[2] Lund Univ, Ctr Chem, S-22100 Lund, Sweden
关键词:
approximation theory;
many-body problems;
phase diagrams;
polymers;
PHASE-BEHAVIOR;
MIXTURES;
MODEL;
D O I:
10.1063/1.3685834
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
We use a continuum chain model and develop an analytical theory for the interaction between many spheres immersed in a fluid of ideal polydisperse polymers. Assuming local spherical symmetry of the polymer field about each particle, combined with a local approximation, compact expressions are derived for the many-body interaction between the spheres. We use a mean-field approximation to investigate the fluid-fluid phase diagram for the mixture. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3685834]
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