Visible-Light-Driven H2 Generation from Water and CO2 Conversion by Using a Zwitterionic Cyclometalated Iridium(III) Complex

被引：61
作者：
Yuan, Yong-Jun [1 ]
Yu, Zhen-Tao [1 ]
Chen, Xiao-Yu [1 ]
Zhang, Ji-Yuan [1 ]
Zou, Zhi-Gang [1 ]
机构：
[1] Nanjing Univ, Ecomat & Renewable Energy Res Ctr, Natl Lab Solid State Microstruct, Dept Mat Sci & Engn, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 46期
基金：
美国国家科学基金会;
关键词：
CO2; reduction; hydrogen production; iridium; visible light; PHOTOINDUCED HYDROGEN-PRODUCTION; EFFICIENT PHOTOCATALYTIC SYSTEM; CARBON-DIOXIDE; MOLECULAR DEVICE; GREENHOUSE-GAS; SOLAR FUELS; TIO2; FILMS; REDUCTION; CATALYSTS; SEMICONDUCTOR;
D O I：
10.1002/chem.201102147
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From light comes hydrogen: Photosensitizer [Ir(4-CF3bt) 2(Hbpdc)] behaves as a very active promoter towards H2 evolution from water when irradiated with visible light (see figure). A remarkable selective-photoreduction for CO2 was also achieved. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12891 / 12895
页数：5
相关论文
共 68 条
  • [1] Reduction of CO2 on a Tricarbonyl Rhenium(I) Complex: Modeling a Catalytic Cycle
    Agarwal, Jay
    Johnson, Richard P.
    Li, Gonghu
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (13) : 2877 - 2881
  • [2] Photocatalytic reduction of CO2 with H2O on titanium oxides anchored within micropores of zeolites: Effects of the structure of the active sites and the addition of Pt
    Anpo, M
    Yamashita, H
    Ichihashi, Y
    Fujii, Y
    Honda, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14): : 2632 - 2636
  • [3] The future of energy supply: Challenges and opportunities
    Armaroli, Nicola
    Balzani, Vincenzo
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (1-2) : 52 - 66
  • [4] Photosynthetic energy conversion: natural and artificial
    Barber, James
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) : 185 - 196
  • [5] Electrocatalytic conversion of CO2 to long carbon-chain hydrocarbons
    Centi, Gabriele
    Perathoner, Siglinda
    Wine, Gauthier
    Gangeri, Miriam
    [J]. GREEN CHEMISTRY, 2007, 9 (06) : 671 - 678
  • [6] Towards Solar Fuels from Water and CO2
    Centi, Gabriele
    Perathoner, Siglinda
    [J]. CHEMSUSCHEM, 2010, 3 (02) : 195 - 208
  • [7] Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes
    Cline, Eric D.
    Adamson, Samantha E.
    Bernhard, Stefan
    [J]. INORGANIC CHEMISTRY, 2008, 47 (22) : 10378 - 10388
  • [8] Mechanism of H2 Evolution from a Photogenerated Hydridocobaloxime
    Dempsey, Jillian L.
    Winkler, Jay R.
    Gray, Harry B.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (47) : 16774 - 16776
  • [9] Chemical reduction of CO2 to different products during photo catalytic reaction on TiO2 under diverse conditions:: an overview
    Dey, G. R.
    [J]. JOURNAL OF NATURAL GAS CHEMISTRY, 2007, 16 (03): : 217 - 226
  • [10] Role of Water and Carbonates in Photocatalytic Transformation of CO2 to CH4 on Titania
    Dimitrijevic, Nada M.
    Vijayan, Baiju K.
    Poluektov, Oleg G.
    Rajh, Tijana
    Gray, Kimberly A.
    He, Haiying
    Zapol, Peter
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (11) : 3964 - 3971
1234567