Activation of sulfur- and nitrogen-containing heterocycles by a dinuclear iridium complex

被引：40
|
作者：
Vicic, DA [1 ]
Jones, WD [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
ORGANOMETALLICS | 1999年 / 18卷 / 02期
关键词：
D O I：
10.1021/om9808007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Cp*IrH3](2) was found to activate both nitrogen- and sulfur-containing heterocycles in the presence of a hydrogen acceptor, giving novel dinuclear organometallic products. In the case of 2-methylthiophene, C-S activation occurred along with a concomitant double hydride transfer and olefin migration to yield a stable adduct. C-H activation alpha to the heteroatom was observed for N-methylpyrrole, and a pyrrole complex containing a rare Ir-Ir triple bond was also isolated. All heterocycle adducts have been structurally characterized.
引用
收藏
页码：134 / 138
页数：5
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