Ligand-free Suzuki-Miyaura Cross-Coupling Reactions of Aryltriazenes with Arylboronic Acids

被引：15

作者：

Nan Guangming ^{[1
,2
]}

Zhu Fanghua ^{[3
]}

Wei Zhijun ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China

[2] Yili Normal Univ, Coll Chem & Biol, Yining 835000, Xinjiang, Peoples R China

[3] China Acad Engn Phys, Res Ctr Laser Fus, Mianyang 621900, Shichuan, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2011年 / 29卷 / 01期

基金：

中国国家自然科学基金;

关键词：

aryltriazenes; Suzuki reaction; arylboronic acids; ligand-free; ARENEDIAZONIUM SALTS; HECK REACTION; DIAZONIUM SALTS; POTASSIUM ARYL; BIARYLS; CATALYST;

D O I：

10.1002/cjoc.201190063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The boron trifluoride induced Suzuki-Miyaura cross-coupling of aryltriazenes with arylboronic acids catalyzed by Pd(OAc)(2) without added ligands has been achieved for the first time. The reactions performed at room temperature under an argon atmosphere give biaryls in good to excellent yields. It is noteworthy that the reactions were conducted under mild and ligand-free conditions.

引用

页码：72 / 78

页数：7

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