Co-promoted Pt catalysts supported on silica aerogel for preferential oxidation of CO

被引:42
作者
Choi, Jinsoon [2 ]
Shin, Chee Burm [2 ]
Suh, Dong Jin [1 ]
机构
[1] Korea Inst Sci & Technol, Clean Technol Res Ctr, Seoul 136971, South Korea
[2] Ajou Univ, Dept Chem Engn, Suwon 442749, Kyunggi, South Korea
关键词
PROX; CO oxidation; silica; aerogel; Pt; Co;
D O I
10.1016/j.catcom.2007.09.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pt and Co doped silica aerogels have been synthesized by sol-gel method and subsequent supercritical drying. Wet-gel state of silica was used in the adsorption process in order to accommodate Pt and Co. Catalytic activities for preferential oxidation of CO in H-2-rich fuels were measured in the temperature range from 25 degrees C to 300 degrees C. At 2500 ppm of carbon monoxide, COPt-SiO2 aerogels showed good activities in a wide range of temperatures maintaining less than 20 ppm at 125-250 degrees C. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:880 / 885
页数:6
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