Catalytic Co-Pyrolysis of Kraft Lignin with Refuse-Derived Fuels Using Ni-Loaded ZSM-5 Type Catalysts

被引：13
作者：
Lee, Hyung Won [1 ]
Cha, Jin Sun [1 ,2 ]
Park, Young-Kwon [1 ]
机构：
[1] Univ Seoul, Sch Environm Engn, Seoul 02504, South Korea
[2] Korea Testing Lab, Seoul 08389, South Korea
来源：
CATALYSTS | 2018年 / 8卷 / 11期
基金：
新加坡国家研究基金会;
关键词：
Kraft lignin; refuse-derived fuels; nickel; desilication; catalytic co-pyrolysis; HIGH-DENSITY POLYETHYLENE; BIOMASS COMPONENTS; OIL; HYDRODEOXYGENATION; POLYPROPYLENE; COPYROLYSIS; CELLULOSE; BIOFUEL; PINE;
D O I：
10.3390/catal8110506
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic co-pyrolysis (CCP) of Kraft lignin (KL) with refuse-derived fuels (RDF) over HZSM-5, Ni/HZSM-5, and NiDHZSM-5 (Ni/desilicated HZSM-5) was carried out using pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS) to determine the effects of the nickel loading, desilication of HZSM-5, and co-pyrolysis of KL with RDF. The catalysts were characterized by Brunauer-Emmett-Teller surface area, X-ray diffraction, and NH3-temperature programed desorption. The nickel-impregnated catalyst improved the catalytic upgrading efficiency and increased the aromatic hydrocarbon production. Compared to KL, the catalytic pyrolysis of RDF produced larger amounts of aromatic hydrocarbons due to the higher H/C-eff ratio. The CCP of KL with RDF enhanced the production of aromatic hydrocarbons by the synergistic effect of hydrogen rich feedstock co-feeding. In particular, Ni/DHZSM-5 showed higher aromatic hydrocarbon formation owing to its higher acidity and mesoporosity.
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页数：11
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