Electrochemical generation of nitrogen-centered radicals for organic synthesis

被引：142

作者：

Chen, Na ^{[1
]}

Xu, Hai -Chao ^{[2
]}

机构：

[1] Huaqiao Univ, Sch Med, Xiamen 361021, Peoples R China

[2] Xiamen Univ, Coll Chem & Chem Engn, Innovat Collaborat Ctr Chem Energy Mat, Key Lab Chem Biol Fujian Prov,State Key Lab Phys C, Xiamen 361005, Peoples R China

来源：

GREEN SYNTHESIS AND CATALYSIS | 2021年 / 2卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Organic electrochemistry; Electrocatalysis; Nitrogen -centered radicals; Radical reactions; INTRAMOLECULAR OXIDATIVE AMINATION; OLEFIN COUPLING REACTIONS; H/N-H FUNCTIONALIZATION; ANODIC-OXIDATION; ELECTROCATALYTIC APPROACH; STEREOSELECTIVE-SYNTHESIS; REGIOSELECTIVE SYNTHESIS; CYCLIZATION REACTIONS; N-HETEROAROMATICS; 3+2 ANNULATION;

D O I：

10.1016/j.gresc.2021.03.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There is a resurgence of interests in organic electrochemistry, which is generally accepted as a green synthetic tool. In this context, many electrochemical methods have been developed in the past decade to access various nitrogen-centered radicals (NCRs) from readily available precursors in a controlled fashion, enabling the rapid development of many NCR-mediated new reactions for the construction of nitrogen-containing organic compounds. In this review, recent advances in the chemistry of electrochemically generated NCRs are critically highlighted, based on the electrochemical strategies for their formation and the types of NCRs. Focus is put on the mechanism for the electrochemical generation of different NCRs and their synthetic applications.

引用

页码：165 / 178

页数：14

共 155 条

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