Low temperature recyclable catalyst for Heck reactions using ultrasound

被引：100
|
作者：
Ambulgekar, GV [1 ]
Bhanage, BM [1 ]
Samant, SD [1 ]
机构：
[1] Univ Bombay, Inst Chem Technol, Dept Chem, Organ Chem Res Lab, Bombay 400019, Maharashtra, India
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 14期
关键词：
Heck reaction; ultrasound; heterogeneous catalysis; palladium leaching; aryl halides;
D O I：
10.1016/j.tetlet.2005.02.035
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Heck reaction of iodobenzene with methyl acrylate in NMP as a solvent has been studied using Pd/C as a catalyst in the presence of ultrasound at room temperature. The ultrasound increased the rate of the reaction. The effect of base, solvent and recyclability of catalyst were studied in the presence of ultrasound and without ultrasound. The reaction only takes place in the presence of ultrasound. The catalyst could be recycled using HCOONa-ultrasound. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2483 / 2485
页数：3
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