Four coordination polymers derived from 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole and copper sulfate

被引：13
作者：
Liu, Kui [1 ]
Zhu, Xia [1 ]
Wang, Ju [1 ]
Li, Baolong [1 ]
Zhang, Yong [1 ]
机构：
[1] Soochow Univ, Coll Chem & Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期
关键词：
Copper sulfate complex; Solvent-controlled assembly; Coordination polymer; 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole; SUPRAMOLECULAR ISOMERS; SPIN-CROSSOVER; COMPLEXES; NETWORKS; CRYSTAL; CHANNELS; SYNERGY; RIBBONS; DESIGN; LAYER;
D O I：
10.1016/j.inoche.2010.05.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole (3-bpt) with copper sulfate in EtOH/H2O solvent yields four coordination polymers [Cu(3-bpt)(H2O)(4)](SO4)center dot H2O (1), [Cu(3-bpt)(H2O)(4)][Cu(3-bpt)(H2O)(3) (SO4)](SO4)center dot 7H(2)O (2), [Cu(3-bpt)(H2O)(3)(SO4)]center dot 2H(2)O (3) and [Cu(3-bpt)(H2O)(SO4)] (4), showing one-dimensional undulated chain, zigzag chain and two-dimensional network. The formations of compounds 1, 2 and 3 are controlled by the EtOH/H2O ratio. The synthesis of compound 4 may be controlled by the EtOH/H2O ratio and the temperature because it is prepared under solvothermal condition. The thermal properties have been investigated. (C) 2010 Elsevier B.V. All rights reserved.
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页码：976 / 980
页数：5
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