Mechanical and water absorption properties of poly(vinyl alcohol)/sago pith waste biocomposites

被引:14
作者
Yee, Toh Wen [1 ]
Choy, Lai Jau [1 ]
Rahman, Wan Aizan Wan Abdul [1 ]
机构
[1] Univ Teknol Malaysia, Fac Chem Engn & Nat Resources, Dept Polymer Engn, Skudai 81310, Johor, Malaysia
关键词
sago pith waste; poly(vinyl alcohol); mechanical properties; water absorption; biodegradable polymer; SAGO STARCH; CHEMICAL MODIFICATION; BLENDS; COMPOSITES; IMPROVEMENT; FILMS; FIBER;
D O I
10.1177/0021998310380287
中图分类号
TB33 [复合材料];
学科分类号
摘要
A series of blends of sago pith waste (SPW) and poly(vinyl alcohol) (PVA) were prepared. Mechanical and water absorption properties of the composites have been investigated. In this study, variable amounts of plasticized SPW (pSPW) and PVA (pPVA) were processed in the presence of glycerol as plasticizers. Composites were compression molded and evaluated. The addition of pSPW reduced the tensile properties of the composites, lowering the elongation and increasing Young's modulus. The reduction in mechanical strength with the addition of pSPW was a general phenomenon due to the poor interfacial adhesion between the pPVA and Pspw, which can be proved by the scanning electron microscope observations. The percentage of water absorbed of the pPVA/pSPW biocomposites was higher than either the pPVA or pSPW alone while pSPW showed better water resistance compared to pPVA because of the restricted mobility exerted by the cellulose fibers. The incorporation of SPW into PVA decreased both the mechanical and water absorption properties.
引用
收藏
页码:1201 / 1207
页数:7
相关论文
共 30 条
  • [1] Physico-chemical characterisation of sage starch
    Ahmad, FB
    Williams, PA
    Doublier, JL
    Durand, S
    Buleon, A
    [J]. CARBOHYDRATE POLYMERS, 1999, 38 (04) : 361 - 370
  • [2] [Anonymous], 2003, D638 ASTM
  • [3] *ASTM, 2007, D4703 ASTM
  • [4] ASTM (American Society for Testing and Materials), 1998, D570 ASTM
  • [5] Plasticized starch-cellulose interactions in polysaccharide composites
    Avérous, L
    Fringant, C
    Moro, L
    [J]. POLYMER, 2001, 42 (15) : 6565 - 6572
  • [6] Properties of biocomposites based on lignocellulosic fillers
    Averous, L.
    Le Digabel, F.
    [J]. CARBOHYDRATE POLYMERS, 2006, 66 (04) : 480 - 493
  • [7] PROPERTIES OF EXTRUDED STARCH-BASED PLASTIC FOAM
    BHATNAGAR, S
    HANNA, MA
    [J]. INDUSTRIAL CROPS AND PRODUCTS, 1995, 4 (02) : 71 - 77
  • [8] BUTTERFLY SRL, 1990, EPA0400531
  • [9] Size exclusion chromatography characterization of thermoplastic starch composites 1. Influence of plasticizer and fibre content
    Carvalho, A
    Zambon, MD
    Curvelo, AAS
    Gandini, A
    [J]. POLYMER DEGRADATION AND STABILITY, 2003, 79 (01) : 133 - 138
  • [10] Biodegradable thermoplastic composites based on polyvinyl alcohol and algae
    Chiellini, Emo
    Cinelli, Patrizia
    Hieva, Vassilka I.
    Martera, Martina
    [J]. BIOMACROMOLECULES, 2008, 9 (03) : 1007 - 1013