PREPARATION AND VISIBLE LIGHT RESPONSIVE PHOTOCATALYTIC ACTIVITY OF Fe3O4/Ni-Al-Ce LDH/Bi2WO6 COMPOSITES

被引:7
作者
Hao, Jiaqi [1 ]
Qu, Ting [1 ]
Wang, Qiufeng [1 ]
Zhao, Zhenbo [1 ]
机构
[1] Changchun Univ Technol, Sch Chem & Life Sci, Changchun 130012, Jilin, Peoples R China
来源
QUIMICA NOVA | 2017年 / 40卷 / 08期
关键词
hydrothermal method; co-precipitation; Fe3O4/Ni-Al-Ce LDH/Bi2WO6 composites; photocatalytic; LAYERED DOUBLE HYDROXIDES; FACILE SYNTHESIS; TIO2; PERFORMANCE; FABRICATION; CORE; MICROSPHERES; DEGRADATION; HETEROSTRUCTURES; HETEROJUNCTIONS;
D O I
10.21577/0100-4042.20170062
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel Fe3O4/Ni-Al-Ce LDH/Bi2WO6 composites were prepared through a hydrothermal method and co-precipitation method. The morphologies and structures of the photocatalysts were characterized by XRD, Raman, TEM, UV-vis-DRS, BET surface area and VSM techniques. The photocatalytic performances of the photocatalysts were investigated by the decolorization of methyl orange (MO) under visible-light irradiation. The results showed that the Fe3O4/Ni-Al-Ce LDH/Bi2WO6 composites exhibited greater photocatalytic activities compared to pure Bi2WO6 and the Ni-Al-Ce LDH; the decolorization rate of MO was 87% within 60 min under visible-light irradiation. The decolorization efficiency of the composite material remained at 71% after 4 recycling runs, showing improved stability. Furthermore, the experimental results also showed that the photocatalytic reactions for the composites followed first-order reaction kinetics. Therefore, the Fe3O4/Ni-Al-Ce LDH/Bi2WO6 composites were photocatalysts with high efficiencies and stabilities for a photocatalytic reaction of an organic pollutant, and this study provides a new, effective method for the development of wastewater treatment.
引用
收藏
页码:849 / 853
页数:5
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