A New Prototype Two-Phase (TiNi)-(β-W) SMA System with Tailorable Thermal Hysteresis

被引:29
作者
Buenconsejo, Pio John S. [1 ]
Zarnetta, Robert [1 ]
Koenig, Dennis [1 ]
Savan, Alan [1 ]
Thienhaus, Sigurd [1 ]
Ludwig, Alfred [1 ]
机构
[1] Ruhr Univ Bochum, Inst Mat, D-44780 Bochum, Germany
关键词
SHAPE-MEMORY ALLOYS; MARTENSITIC-TRANSFORMATION; PHASE-TRANSFORMATIONS; THIN-FILMS; BEHAVIOR; STRESS; CU;
D O I
10.1002/adfm.201001697
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Ti-Ni-W two-phase shape memory alloy (SMA) thin film system is presented as a prototype for new SMAs with tailorable thermal transformation hysteresis (Delta T). The concept is to combine the SMA TiNi with almost insoluble W to create the two-phase system (TiNi)-(beta-W). This system behaves like a pseudobinary TiNi system. Phase transformation behavior for compositions above the solubility limit of W in TiNi exhibit a B2-R phase transformation with characteristically small Delta T. Moreover, Delta T is dependent on the amount of W and it can be tailored to zero and even negative. This phenomenon is rationalized as being due to the mechanical interaction between the phases B2-TiNi and beta-W. The presented results are very promising for the development of high-speed Ti-Ni-based SMA actuators.
引用
收藏
页码:113 / 118
页数:6
相关论文
共 34 条
[1]  
[Anonymous], 2009, Thin film shape memory alloys fundamentals and device applications
[2]   Combinatorial search of thermoelastic shape-memory alloys with extremely small hysteresis width [J].
Cui, J ;
Chu, YS ;
Famodu, OO ;
Furuya, Y ;
Hattrick-Simpers, J ;
James, RD ;
Ludwig, A ;
Thienhaus, S ;
Wuttig, M ;
Zhang, ZY ;
Takeuchi, I .
NATURE MATERIALS, 2006, 5 (04) :286-290
[3]   PHASE-TRANSFORMATIONS IN TERNARY TINIX ALLOYS [J].
EDMONDS, KR ;
HWANG, CM .
SCRIPTA METALLURGICA, 1986, 20 (05) :733-737
[4]  
Enami K., 1995, J PHYS, V5, pC8
[5]   Influence of Ni on martensitic phase transformations in NiTi shape memory alloys [J].
Frenzel, J. ;
George, E. P. ;
Dlouhy, A. ;
Somsen, Ch. ;
Wagner, M. F. -X. ;
Eggeler, G. .
ACTA MATERIALIA, 2010, 58 (09) :3444-3458
[6]   Relaxation and recovery of extrinsic stress in sputtered titanium-nickel thin films on (100)-Si [J].
Grummon, DS ;
Zhang, JP ;
Pence, TJ .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 273 :722-726
[7]   Martensitic transformation and two-way shape memory effect of sputter-deposited Ni-rich Ti-Ni alloy films [J].
Gyobu, A ;
Kawamura, Y ;
Horikawa, H ;
Saburi, T .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 273 :749-753
[8]  
HONMA T, 1980, P 4 INT C TIT 80 AIM, P1455
[9]   Transformation sequence and second phases in ternary Ti-Ni-W shape memory alloys with less than 2 at % W [J].
Hsieh, SF ;
Wu, SK ;
Lin, HC ;
Yang, CH .
JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 387 (1-2) :121-127
[10]   A study on the nickel-rich ternary Ti-Ni-Al shape memory alloys [J].
Hsieh, SF ;
Wu, SK .
JOURNAL OF MATERIALS SCIENCE, 1997, 32 (04) :989-996