Artificial photosynthesis: Catalytic water oxidation and CO2 reduction by dinuclear non-noble-metal molecular catalysts

被引：87
作者：
Wang, Jia-Wei [1 ,2 ]
Zhong, Di-Chang [1 ]
Lu, Tong-Bu [1 ,2 ]
机构：
[1] Tianjin Univ Technol, Sch Mat Sci & Engn, Inst New Energy Mat & Low Carbon Technol, Tianjin 300384, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
来源：
COORDINATION CHEMISTRY REVIEWS | 2018年 / 377卷
基金：
国家重点研发计划;
关键词：
Non-noble metal; Synergistic effect; Dinuclear complex; Artificial photosynthesis; Molecular catalyst; EFFICIENT ELECTROCATALYTIC CO2; CARBON-DIOXIDE ACTIVATION; OXYGEN-EVOLVING CATALYST; O BOND FORMATION; ELECTROCHEMICAL REDUCTION; PHOTOCHEMICAL REDUCTION; HOMOGENEOUS ELECTROCATALYST; NEUTRAL PH; COMPLEX; MANGANESE;
D O I：
10.1016/j.ccr.2018.09.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The realization of artificial photosynthesis is of intense interest as it can be an effective solution to relieve the energy crisis. Besides hydrogen evolution and some organic oxidation reactions, water oxidation and CO2 reduction reactions are two crucial alternative half-reactions that can be coupled to form a classic artificial photosynthetic system. Both of them are energy-demanding and thus show slow reaction rates without appropriate catalysts. Dinuclear non-noble metal complexes are promising candidates as bioinspired mediators to facilitate both reactions through the potential synergistic catalytic effect between two metal sites. In this Review, key advancements in dinuclear non-noble metal complexes as the molecular catalysts for water oxidation and CO2 reduction reactions have been highlighted to provide a future perspective. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：225 / 236
页数：12
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共 134 条
  • [1] A structural phylogenetic map for chloroplast photosynthesis
    Allen, John F.
    de Paula, Wilson B. M.
    Puthiyaveetil, Sujith
    Nield, Jon
    [J]. TRENDS IN PLANT SCIENCE, 2011, 16 (12) : 645 - 655
  • [2] Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex
    Angamuthu, Raja
    Byers, Philip
    Lutz, Martin
    Spek, Anthony L.
    Bouwman, Elisabeth
    [J]. SCIENCE, 2010, 327 (5963) : 313 - 315
  • [3] Dinuclear manganese complexes for water oxidation: evaluation of electronic effects and catalytic activity
    Arafa, Wael A. A.
    Karkas, Markus D.
    Lee, Bao-Lin
    Akermark, Torbjorn
    Liao, Rong-Zhen
    Berends, Hans-Martin
    Messinger, Johannes
    Siegbahn, Per E. M.
    Akermark, Bjorn
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (24) : 11950 - 11964
  • [4] Splitting Water with Cobalt
    Artero, Vincent
    Chavarot-Kerlidou, Murielle
    Fontecave, Marc
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) : 7238 - 7266
  • [5] Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion
    Azcarate, Iban
    Costentin, Cyrille
    Robert, Marc
    Saveant, Jean-Michel
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (51) : 16639 - 16644
  • [6] NICKEL(II) CYCLAM - AN EXTREMELY SELECTIVE ELECTROCATALYST FOR REDUCTION OF CO2 IN WATER
    BELEY, M
    COLLIN, JP
    RUPPERT, R
    SAUVAGE, JP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (19) : 1315 - 1316
  • [7] Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels
    Benson, Eric E.
    Kubiak, Clifford P.
    Sathrum, Aaron J.
    Smieja, Jonathan M.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) : 89 - 99
  • [8] Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances
    Bonin, Julien
    Maurin, Antoine
    Robert, Marc
    [J]. COORDINATION CHEMISTRY REVIEWS, 2017, 334 : 184 - 198
  • [9] Dye-Sensitized Hydrobromic Acid Splitting for Hydrogen Solar Fuel Production
    Brady, Matthew D.
    Sampaio, Renato N.
    Wang, Degao
    Meyer, Thomas J.
    Meyer, Gerald J.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (44) : 15612 - 15615
  • [10] The synergistic catalysis effect within a dinuclear nickel complex for efficient and selective electrocatalytic reduction of CO2 to CO
    Cao, Li-Ming
    Huang, Hai-Hua
    Wang, Jia-Wei
    Zhong, Di-Chang
    Lu, Tong-Bu
    [J]. GREEN CHEMISTRY, 2018, 20 (04) : 798 - 803
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