Aluminum containing periodic mesoporous organosilicas: synthesis and etherification

被引:0
作者
Kim, JW [1 ]
Lee, HI
Kim, JM
Yuan, X
Yie, JE
机构
[1] Ajou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South Korea
[2] Ajou Univ, Dept Mol Sci & Technol, Funct Mat Lab, Suwon 442749, South Korea
[3] Fushun Petr Univ, Dept Petrochem Technol, Fushun 113001, Peoples R China
来源
NANOTECHNOLOGY IN MESOSTRUCTURED MATERIALS | 2003年 / 146卷
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Aluminum has been successfully incorporated within the frameworks of periodic mesoporous organosilicas (Al-PMO) by co-condensation of bis(triethoxysilyl)ethane and dibutoxyaluminotriethoxysilane. The Al-PMO materials exhibit highly ordered 2-d hexagonal structures, high surface areas, and narrow pore size distribution in the mesoporous range. The Al-PMO catalysts result in excellent catalytic activity and selectivity for etherification reaction between 2-naphthol and ethanol, which is comparable with those of beta zeolite.
引用
收藏
页码:665 / 668
页数:4
相关论文
共 5 条
  • [1] Periodic mesoporous organosilicas with organic groups inside the channel walls
    Asefa, T
    MacLachlan, MJ
    Coombs, N
    Ozin, GA
    [J]. NATURE, 1999, 402 (6764) : 867 - 871
  • [2] Amine-functionalized periodic mesoporous organosilicas
    Burleigh, MC
    Markowitz, MA
    Spector, MS
    Gaber, BP
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (12) : 4760 - 4766
  • [3] Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks
    Inagaki, S
    Guan, S
    Fukushima, Y
    Ohsuna, T
    Terasaki, O
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) : 9611 - 9614
  • [4] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM
    KRESGE, CT
    LEONOWICZ, ME
    ROTH, WJ
    VARTULI, JC
    BECK, JS
    [J]. NATURE, 1992, 359 (6397) : 710 - 712
  • [5] Etherification of β-naphthol with alkanols using modified clays and sulfated zirconia
    Yadav, GD
    Krishnan, MS
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (08) : 3358 - 3365