Aluminum containing periodic mesoporous organosilicas: synthesis and etherification
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作者:
Kim, JW
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Ajou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South KoreaAjou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South Korea
Kim, JW
[1
]
Lee, HI
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机构:Ajou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South Korea
Lee, HI
Kim, JM
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机构:Ajou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South Korea
Kim, JM
Yuan, X
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机构:Ajou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South Korea
Yuan, X
Yie, JE
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机构:Ajou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South Korea
Yie, JE
机构:
[1] Ajou Univ, Sch Chem Engn & Biotechnol, Catalyst & Surface Lab, Suwon 441749, South Korea
[2] Ajou Univ, Dept Mol Sci & Technol, Funct Mat Lab, Suwon 442749, South Korea
[3] Fushun Petr Univ, Dept Petrochem Technol, Fushun 113001, Peoples R China
来源:
NANOTECHNOLOGY IN MESOSTRUCTURED MATERIALS
|
2003年
/
146卷
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D O I:
暂无
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Aluminum has been successfully incorporated within the frameworks of periodic mesoporous organosilicas (Al-PMO) by co-condensation of bis(triethoxysilyl)ethane and dibutoxyaluminotriethoxysilane. The Al-PMO materials exhibit highly ordered 2-d hexagonal structures, high surface areas, and narrow pore size distribution in the mesoporous range. The Al-PMO catalysts result in excellent catalytic activity and selectivity for etherification reaction between 2-naphthol and ethanol, which is comparable with those of beta zeolite.