Malonates in cyclocondensation reactions

被引：44

作者：

Stadlbauer, W ^{[1
]}

Badawey, ES ^{[1
]}

Hojas, G ^{[1
]}

Roschger, P ^{[1
]}

Kappe, T ^{[1
]}

机构：

[1] Karl Franzens Univ Graz, Organ Synth Grp, Dept Chem, A-8010 Graz, Austria

来源：

MOLECULES | 2001年 / 6卷 / 04期

关键词：

ethyl malonates; (chlorocarbonyl)ketenes; bis(2,4,6-trichlorophenyl) malonates; bis(trimethylsilyl) malonates; sixmembered heterocycles;

D O I：

10.3390/60400338

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The use of malonates such as diethyl malonates 9, (chlorocarbonyl)ketenes 15 and bis(2,4,6-trichlorophenyl) malonates 18 as reagents for cyclocondensation with 1,3-dinucleophiles to give six-membered heterocycles is described, Further attempts to use malonates such as bis(:trimethylsilyl) malonates 19 and bis(carbamimidoyl) malonates 29 as new cyclocondensation agents are described.

引用

页码：338 / 352

页数：15

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