Catalytic Conversion of Anisole: Evidence of Oxygen Removal in Reactions with Hydrogen

被引：63

作者：

Runnebaum, Ron C. ^{[1
]}

Nimmanwudipong, Tarit ^{[1
]}

Block, David E. ^{[1
,2
]}

Gates, Bruce C. ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA

[2] Univ Calif Davis, Dept Viticulture & Enol, Davis, CA 95616 USA

来源：

CATALYSIS LETTERS | 2011年 / 141卷 / 06期

关键词：

Anisole; Zeolite Y; Supported platinum; Transalkylation; Hydrodeoxygenation; BIOMASS PYROLYSIS OIL; HZSM-5; ZEOLITE; TRANSFORMATION; COMPONENTS;

D O I：

10.1007/s10562-010-0510-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conversion of anisole, a prototypical bio-oil compound, was catalyzed by Pt/Al2O3 in the presence of H-2 at 573 K, with the selectivity for C-O bond breaking approximately matching that for ring hydrogenation; these reactions were accompanied by methyl group transfers matching those in the conversion catalyzed by HY zeolite.

引用

页码：817 / 820

页数：4

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