The nanocrystalline forming by combustion synthesis of Ti (Zr) hydrides

被引：16

作者：

Shekhtman, VS ^{[1
]}

Dolukhanyan, SK

Abrosimova, GE

Abrahamyan, KA

Aleksanyan, AG

Aghajanyan, NN

Ter-Galstyan, OP

机构：

[1] Inst Solid State Phys, Chernogolovka 142432, Russia

[2] Inst Phys Chem, Yerevan 375044, Armenia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2001年 / 26卷 / 05期

关键词：

self-propagating high temperature synthesis (SHS); nanoscale hydrides and hydridonitrides;

D O I：

10.1016/S0360-3199(00)00075-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The experimental data concerning nanoscale hydrides of transition metals, obtained by synthesis in combustion wave are presented. The systems TI-H, Zr-H, Ti-N-H, Zr-N-H. Ti-Zr-N-H were studied. In all samples, the dimensions of grains were as low as 50 nm. The peculiarities of self-propagating high-temperature synthesis processing and structure causes of this phenomena are discussed. The relations between cubic structure of TiH2 hydride and hexagonal structure of Ti-hydridonitride were demonstrated. (C) 2001 International Association for Hydrogen Energy. Published by Elsevier Science Ltd. All rights reserved.

引用

页码：435 / 440

页数：6