Adsorption of Ni2+ and Cu2+ from Aqueous Solution by Polyethylenimine Impregnation of Metal-Organic Frameworks

被引：3

作者：

Wang, Dan ^{[1
]}

Xiao, Xinfeng ^{[1
]}

Han, Bo ^{[1
]}

Ni, Weiming ^{[1
]}

Gao, Yu ^{[1
]}

Li, Lin ^{[1
]}

Xue, Jianliang ^{[1
]}

机构：

[1] Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266510, Peoples R China

来源：

NANO | 2020年 / 15卷 / 03期

关键词：

Adsorption; metal-organic frameworks; polyethylenimine; Ni2+; Cu2+; INORGANIC HYBRID SILICA; SIMULTANEOUS REMOVAL; SELECTIVE REMOVAL; BINDING-AGENT; HEAVY-METALS; IONS; CU(II); CR(VI); DEGRADATION; ADSORBENT;

D O I：

10.1142/S1793292020500290

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A series of UiO-66-PEI materials were obtained by impregnating UiO-66 with different amounts of polyethylenimine (PEI) with UiO-66 as the basic skeleton material. The materials were used as adsorbents to remove Ni2+ and Cu2+ from water. The prepared UiO-66-PEI-30 had good adsorption capacity on Ni2+ and Cu2+ at 30% PEI. The adsorption of Ni2+ and Cu2+ with UiO-66-PEI-30 was further studied. The role of eluent types, elution time, concentration and volume on the effect of Cu2+ elution was investigated. The adsorption of Ni2+ and Cu2+ by UiO-66-PEI-30 followed the pseudo-second-order kinetic model and Langmuir adsorption model. The maximum adsorption capacities obtained by Langmuir fitting for Ni2+ and Cu2+ were 11.54 mg g(-1) and 24.87 mg g(-1), respectively. After four desorption/adsorption experiments, UiO-66-PEI-30 still showed good adsorption performance. UiO-66 impregnated with PEI was an adsorbent with adsorption potential.

引用

页数：11

共 49 条

[1] Iron and Copper Recovery/Removal from Industrial Wastes: A Review [J].

Agrawal, Archana ;

Kumari, S. ;

Sahu, K. K. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (13) :6145-6161

[2] Chelating adsorption properties of PEI/SiO2 for plumbum ion [J].

An, Fuqiang ;

Gao, Baojiao .

JOURNAL OF HAZARDOUS MATERIALS, 2007, 145 (03) :495-500

[3] Iron(III) ion removal from solution through adsorption on chitosan [J].

Burke, A ;

Yilmaz, E ;

Hasirci, N ;

Yilmaz, O .

JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 84 (06) :1185-1192

[4] Removal of chromium from electroplating industry effluents by ion exchange resins [J].

Cavaco, Sofia A. ;

Fernandes, Sandra ;

Quina, Margarida M. ;

Ferreira, Licinio M. .

JOURNAL OF HAZARDOUS MATERIALS, 2007, 144 (03) :634-638

[5] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[6] Poly(allylamine)-Mesoporous Silica Composite Materials for CO2 Capture from Simulated Flue Gas or Ambient Air [J].

Chaikittisilp, Watcharop ;

Khunsupat, Ratayakorn ;

Chen, Thomas T. ;

Jones, Christopher W. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (24) :14203-14210

[7] Adsorption of Cr(VI) from Aqueous Solution by Ethylenediaminetetraacetic Acid-Chitosan-Modified Metal-Organic Framework [J].

Deng, Yu-Ying ;

Xiao, Xin-Feng ;

Wang, Dan ;

Han, Bo ;

Gao, Yu ;

Xue, Jian-Liang .

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2020, 20 (03) :1660-1669

[8] Use of polymer-bound Schiff base as a new liquid binding agent of diffusive gradients in thin-films for the measurement of labile Cu2+, Cd2+ and Pb2+ [J].

Fan, Hong-Tao ;

Liu, Jin-Xiu ;

Sui, Dian-Peng ;

Yao, Hui ;

Yan, Feng ;

Sun, Ting .

JOURNAL OF HAZARDOUS MATERIALS, 2013, 260 :762-769

[9] Adsorption of lead(II) from aqueous solution using a poly (ethyleneimine)-functionalized organic-inorganic hybrid silica prepared by hydrothermal-assisted surface grafting method [J].

He, Lu ;

Liu, Dan-Dan ;

Wang, Bing-Bing ;

Xu, Hong-Bo .

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2014, 9 (06) :800-809

[10] Poly(ethyleneimine)-functionalized Silica-supported Organic-Inorganic Hybrid Sorbent Prepared by Combining Sol-Gel Method and Hydrothermal-assisted Process [J].

He, Lu ;

Liu, Dan-Dan ;

Wang, Bing-Bing ;

Liu, Na .

CHEMISTRY LETTERS, 2014, 43 (05) :579-581

← 1 2 3 4 5 →