Overcoming the Challenges of Large-Area High-Efficiency Perovskite Solar Cells

被引：148

作者：

Kim, Jincheol ^{[1
]}

Yun, Jae Sung ^{[1
]}

Cho, Yongyoon ^{[1
]}

Lee, Da Seul ^{[1
]}

Wilkinson, Benjamin ^{[1
]}

Soufiani, Arman Mahboubi ^{[1
]}

Deng, Xiaofan ^{[1
]}

Zheng, Jianghui ^{[1
]}

Shi, Adrian ^{[1
]}

Lim, Sean ^{[2
]}

Chen, Sheng ^{[1
]}

Hameiri, Ziv ^{[1
]}

Zhang, Meng ^{[1
]}

Lau, Cho Fai Jonathan ^{[1
]}

Huang, Shujuan ^{[1
]}

Green, Martin A. ^{[1
]}

Ho-Baillie, Anita W. Y. ^{[1
]}

机构：

[1] Univ New South Wales, Sch Photovolta & Renewable & Engn, ACAP, Sydney, NSW 2052, Australia

[2] Univ New South Wales, Electron Microscope Unit, Sydney, NSW 2052, Australia

来源：

ACS ENERGY LETTERS | 2017年 / 2卷 / 09期

关键词：

CRYSTAL-GROWTH; IDENTIFICATION; NUCLEATION; LAYERS;

D O I：

10.1021/acsenergylett.7b00573

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the first time, we report large-area (16 cm(2)), independently certified efficient single perovskite solar cells (PSCs) by overcoming two challenges associated with large area perovskite solar cells. The first challenge of realizing a homogeneous and densely packed perovskite film over a large area is overcome by using an antisolvent spraying process. The second challenge of removing the series resistance limitation of transparent conductor is overcome by incorporating a metal grid designed using a semidistributed diode model. A 16 cm2 perovskite solar device at the cell level rather than at the module level is demonstrated using the modified solution process in conjunction with the use of a metal grid. The cell is independently certified to be 12.1% efficient. This work paves the way toward highly efficient and large perovskite cells without single-junction perovskite solar cells and silicon perovskite tandems.

引用

页码：1978 / 1984

页数：7

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